水溶性NaYF4:Eu^3+@Ag核-壳纳米晶的下转换荧光及其在葡萄糖检测中的应用
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| Published in | 中国科学:材料科学(英文版) Vol. 60; no. 1; pp. 68 - 74 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
2017
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| Subjects | |
| Online Access | Get full text |
| ISSN | 2095-8226 2199-4501 |
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| Bibliography: | Techniques for detecting glucose are developing at a breathtaking speed because diabetes mellitus can cause many serious complications, such as blindness, high blood pressure heart disease and kidney failure. Herein, water sol- uble NaYF4:Eu^3+@Ag core-shell nanocrystals for glucose de- tection with lower detection limit have been successfully de- veloped, using NaYF4:Eu^3+ cores as the energy donors and Ag shells as the efficient quenchers through energy transfer. After immobilization of glucose oxidase (GOx) on the sur- face of NaYF4:Eu^3+@Ag core-shell nanocrystals, the Ag shells can be decomposed in the presence of glucose, accompanied by down-shifting luminescence recovery. The limit of detec- tion of NaYF4:Eu^3+@Ag was 0.12 μmol L^-1. Therefore, the NaYF4:Eu^3+@Ag can be easily extended to the detection of a variety of H2O2-involved analytes. NaYF4:Eu^3+@Ag, nanocrystals, luminescence, glu-cose Di Wang1, Ruihong Wang1, Lijuan Liu1, Yang Qu1, Guofeng Wang1. and Yadong Li2 1 Key Laboratory of Functional Inorganic Materials Chemistry (Ministry of Education), School of Chemistry and Materials Science, Heilongjiang Uni- versity, Harbin 150080, China 2 Department of Chemistry, Tsinghua University, Beijing 100084, China |
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| ISSN: | 2095-8226 2199-4501 |