水溶性NaYF4:Eu^3+@Ag核-壳纳米晶的下转换荧光及其在葡萄糖检测中的应用

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Published in中国科学:材料科学(英文版) Vol. 60; no. 1; pp. 68 - 74
Main Author 王迪 王瑞红 刘丽娟 曲阳 王国凤 李亚栋
Format Journal Article
LanguageEnglish
Published 2017
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ISSN2095-8226
2199-4501

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Bibliography:Techniques for detecting glucose are developing at a breathtaking speed because diabetes mellitus can cause many serious complications, such as blindness, high blood pressure heart disease and kidney failure. Herein, water sol- uble NaYF4:Eu^3+@Ag core-shell nanocrystals for glucose de- tection with lower detection limit have been successfully de- veloped, using NaYF4:Eu^3+ cores as the energy donors and Ag shells as the efficient quenchers through energy transfer. After immobilization of glucose oxidase (GOx) on the sur- face of NaYF4:Eu^3+@Ag core-shell nanocrystals, the Ag shells can be decomposed in the presence of glucose, accompanied by down-shifting luminescence recovery. The limit of detec- tion of NaYF4:Eu^3+@Ag was 0.12 μmol L^-1. Therefore, the NaYF4:Eu^3+@Ag can be easily extended to the detection of a variety of H2O2-involved analytes.
NaYF4:Eu^3+@Ag, nanocrystals, luminescence, glu-cose
Di Wang1, Ruihong Wang1, Lijuan Liu1, Yang Qu1, Guofeng Wang1. and Yadong Li2 1 Key Laboratory of Functional Inorganic Materials Chemistry (Ministry of Education), School of Chemistry and Materials Science, Heilongjiang Uni- versity, Harbin 150080, China 2 Department of Chemistry, Tsinghua University, Beijing 100084, China
ISSN:2095-8226
2199-4501