Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO2
An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO2. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carbo...
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| Published in | RSC advances Vol. 9; no. 56; pp. 32628 - 32633 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
2019
The Royal Society of Chemistry |
| Subjects | |
| Online Access | Get full text |
| ISSN | 2046-2069 2046-2069 |
| DOI | 10.1039/c9ra05253d |
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| Abstract | An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO2. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides. |
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| AbstractList | An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO2. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides.An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO2. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides. An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO2. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides. An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO 2 . β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides. An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO 2 . |
| Author | Wang, Huan Yang-Chun, Lan Wang, Hui La-Xia, Wu Ying-Guo, Zhao Ye-Bin Guan Jia-Xing, Lu |
| Author_xml | – sequence: 1 givenname: Wu surname: La-Xia fullname: La-Xia, Wu – sequence: 2 givenname: Zhao surname: Ying-Guo fullname: Ying-Guo, Zhao – sequence: 3 fullname: Ye-Bin Guan – sequence: 4 givenname: Hui surname: Wang fullname: Wang, Hui – sequence: 5 givenname: Lan surname: Yang-Chun fullname: Yang-Chun, Lan – sequence: 6 givenname: Huan surname: Wang fullname: Wang, Huan – sequence: 7 givenname: Lu surname: Jia-Xing fullname: Jia-Xing, Lu |
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| Copyright | Copyright Royal Society of Chemistry 2019 This journal is © The Royal Society of Chemistry. This journal is © The Royal Society of Chemistry 2019 The Royal Society of Chemistry |
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| Snippet | An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO2.... An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO 2 .... |
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| SubjectTerms | Aromatic compounds Carbon dioxide Carboxylic acids Catalysts Chemical synthesis Chemistry Chlorides Coordination compounds Copper Halides Selectivity Silver |
| Title | Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO2 |
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