Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO2

An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO2. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carbo...

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Bibliographic Details
Published inRSC advances Vol. 9; no. 56; pp. 32628 - 32633
Main Authors La-Xia, Wu, Ying-Guo, Zhao, Ye-Bin Guan, Wang, Hui, Yang-Chun, Lan, Wang, Huan, Jia-Xing, Lu
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 2019
The Royal Society of Chemistry
Subjects
Aromatic compounds
Carbon dioxide
Carboxylic acids
Catalysts
Chemical synthesis
Chemistry
Chlorides
Coordination compounds
Copper
Halides
Selectivity
Silver
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ISSN2046-2069
2046-2069
DOI10.1039/c9ra05253d

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Summary:An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO2. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides.
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ISSN:2046-2069
2046-2069
DOI:10.1039/c9ra05253d