Homogeneous Light‐Driven Catalytic Direct Carboxylation with CO2

Carbon dioxide is a ubiquitous and inexpensive one‐carbon source for chemical synthesis, and the efficient incorporation of CO2 into organic molecules is of widespread research interest both for economic and ecological reasons. The methodologies to employ carbon dioxide as a single‐carbon unit to co...

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Bibliographic Details
Published inChinese journal of chemistry Vol. 36; no. 6; pp. 545 - 554
Main Authors Tan, Fen, Yin, Guoyin
Format Journal Article
LanguageEnglish
Published Weinheim WILEY‐VCH Verlag GmbH & Co. KGaA 01.06.2018
Wiley Subscription Services, Inc
Subjects
Agrochemicals
Carbon dioxide
Carbon sources
Carboxylation
Catalysis
Chemical synthesis
green chemistry
homogeneous catalysis
Molecular chains
Organic chemistry
photocatalysis
Photoredox catalysis
Reagents
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ISSN1001-604X
1614-7065
DOI10.1002/cjoc.201800011

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Summary:Carbon dioxide is a ubiquitous and inexpensive one‐carbon source for chemical synthesis, and the efficient incorporation of CO2 into organic molecules is of widespread research interest both for economic and ecological reasons. The methodologies to employ carbon dioxide as a single‐carbon unit to construct molecules relevant for agrochemical and pharmaceutical research include many elegant approaches, including asymmetric transformations. Even though remarkable achievements have been made in the field of light‐driven catalysis, especially photoredox catalysis, homogeneous light‐driven catalytic carboxylation by employing CO2 as the key reagent has only become a subject of increasing attention in recent years. Therefore, this concise review will discuss the latest advances in this research area.
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ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201800011