Highly lubricating and wear‐resistant Ti3C2Tx@SiO2/PI composites based on the action of transfer film at the friction surface

• Published in: Polymer composites Vol. 45; no. 7; pp. 6332 - 6343
• Main Authors: Chen, Guojing, Ma, Zhenqian, Jiang, Shuai, Wang, Xinrui, Huang, Yufei, Chai, Chunpeng
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 10.05.2024; Blackwell Publishing Ltd
• Subjects: coefficient of friction; Composite materials; Interlayers; Lubricants & lubrication; Lubricating properties; Lubricity; Material properties; Mechanical components; polyimide; Polyimide resins; Rolling resistance; Silicon dioxide; Sliding friction; Solid lubricants; Ti3C2Tx; Tribology; Wear rate; Wear resistance; Wear resistant
• ISSN: 0272-8397; 1548-0569
• DOI: 10.1002/pc.28200

Polyimide (PI) is a special engineering plastic, widely involved in mechanical components, instruments, and petrochemicals. However, single PI material is inevitably subject to wear and tear in practice, which leads to weakened material properties. In this work, Ti3C2Tx@SiO2 was prepared to enhance the wear resistance and lubrication properties of PI by intercalating SiO2 into the interlayer of Ti3C2Tx sheets. Ti3C2Tx@SiO2/PI composites were fabricated in two steps to test the tribological performances. SiO2 particles change the form of interfacial friction from sliding to rolling, thus relieving direct friction between material and steel ball. So, the composites have a minimum COF (COF = 0.33) when the content of Ti3C2Tx@SiO2 is 0.80 wt%. Moreover, the average value of wear rate was 0.24 × 10−5 mm3/(N·m) when Ti3C2Tx@SiO2 content was 1.60 wt%, which was 91.0% lower compared to the PI matrix. During the friction process, the abrasive chips of the material migrate to the surface of the steel ball to form a transfer film, which protects the material and thus reduces the wear rate. Therefore, the hybrids Ti3C2Tx@SiO2 are effective and important wear‐resistant agents and solid lubricants to improve the wear resistance and lubricity of PI or other polymer materials. Highlights SiO2 insert Ti3C2Tx is a key factor in changing sliding friction into rolling friction, effectively reducing the COF. The average wear rate was 91.0% lower than that of the polyimide matrix when Ti3C2Tx@SiO2 content was 1.60 wt%. The minimum COF of Ti3C2Tx@SiO2/PI composites reached 0.33 when the content of Ti3C2Tx@SiO2 was 0.80 wt%. The transfer film effectively reduces further wear of the material during friction. Hybrid Ti3C2Tx@SiO2 effectively improved the lubrication and wear resistance of polyimide through the surface tribological action of the transfer film.