SmI2-mediated intermolecular addition-elimination of piperidine and pyrrolidine N-α-radicals with arylacetylene sulfones

An efficient approach to access alpha-arylacetylene-substituted pyrrolidine and piperidine derivatives has been developed through a samarium diiodide-mediated addition-elimination process of pyrrolidine and piperidine N-alpha-radicals with arylacetylene sulfones.

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 58; no. 77; pp. 10841 - 10844
Main Authors Liu, Chang-Hong, Guo, Jia-Ming, Li, Xin, Sun, Jian-Ting, Wei, Bang-Guo, Si, Chang-Mei
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 27.09.2022
Royal Society of Chemistry
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Piperidine
Samarium
Science & Technology
Sulfones
FUNCTIONALIZATION
ASYMMETRIC-SYNTHESIS
CATION POOL
CARBON
AMINES
ACIDS
BONDS
GENERATION
ALKYNYLATION
Online AccessGet full text
ISSN1359-7345
1364-548X
1364-548X
DOI10.1039/d2cc03984b

Cover

More Information
Summary:An efficient approach to access alpha-arylacetylene-substituted pyrrolidine and piperidine derivatives has been developed through a samarium diiodide-mediated addition-elimination process of pyrrolidine and piperidine N-alpha-radicals with arylacetylene sulfones.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
content type line 23
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d2cc03984b