Synthesis of core/shell structured Pd₃Au@Pt/C with enhanced electrocatalytic activity by regioselective atomic layer deposition combined with a wet chemical method

• Published in: RSC advances Vol. 6; no. 71 p.66712-66720; pp. 66712 - 66720
• Main Authors: Liu, Huiyuan, Song, Yujiang, Li, Shushuang, Li, Jia, Liu, Yuan, Jiang, Ying-Bing, Guo, Xinwen
• Format: Journal Article
• Language: English
• Published: 01.01.2016
• Subjects: carbon; catalytic activity; electrochemistry; formic acid; metals; micelles; nanoparticles; oxidation; regioselectivity; surfactants; transmission electron microscopy; X-ray diffraction; X-ray photoelectron spectroscopy
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/c6ra04990g

We report the synthesis of Pd₃Au@Pt/C by atomic layer deposition (ALD) combined with a wet chemical method. Initially, nearly uniform Pd₃Au nanoparticles (NPs) (∼4.7 nm) supported on carbon with a loading of ∼20 wt% were prepared by reducing metal complexes confined in reverse micelles adsorbed on carbon. Next, a Pt thin layer (less than 1 nm) was selectively deposited on purified Pd₃Au particles instead of on carbon by regioselective ALD that likely arises from the coverage of nucleation sites on carbon by surfactant molecules in conjunction with catalytic decomposition of the Pt precursor on Pd₃Au. The resulting core–shell structured material was subject to TEM, HAADF-STEM/EDX, XRD, XPS and electrochemical measurements. Interestingly, Pd₃Au@Pt/C demonstrates a significantly improved electrocatalytic activity toward both formic acid oxidation reaction (FAOR) and oxygen reduction reaction (ORR) compared with Pd₃Au/C and state-of-the art Pt/C. This study opens up a unique avenue for the synthesis core/shell structured materials with potential applications in catalysis, electrocatalysis, and so on.