인이 도핑된 NiCo₂O₄ 전극 제조 공정의 간소화를 통한 전극 특성의 변화

• Published in: Biuletyn Uniejowski Vol. 56; no. 5; pp. 299 - 308
• Main Authors: 이석희(Seokhee-Lee), 차현진(Hyunjin Cha), 박정환(Jeonghwan Park), 손영국(Young Guk Son), 황동현(Donghyun Hwang)
• Format: Journal Article
• Language: Korean
• Published: 한국표면공학회 01.10.2023
• Subjects: 기계공학; Supercapacitor; Energy Storage Device; NiCo₂O; Electrode; Hydrothermal Method; Phosphorus Doping
• ISSN: 1225-8024; 2299-8403; 2288-8403
• DOI: 10.5695/JSSE.2023.56.5.299

In this study, phosphorus (P)-doped nickel cobaltite (P-NiCo2O4) and nickel-cobalt layered double hydroxide (P-NiCo-LDH) were synthesized on nickel (Ni) foam as a conductive support using hydrothermal synthesis. The thermal properties, crystal structure, microscopic surface morphology, chemical distribution, electronic state of the constituent elements on the sample surface, and electrical properties of the synthesized P-NiCo2O4 and P-NiCo-LDH samples were analyzed using thermogravimetric analysis-differential scanning calorimetry (TGA-DSC), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The P-NiCo2O4 electrode exhibited a specific capacitance of 1,129 Fg-1 at a current density of 1 Ag-1, while the P-NiCo-LDH electrode displayed a specific capacitance of 1,012 Fg-1 at a current density of 1 Ag-1. When assessing capacity changes for 3,000 cycles, the P-NiCo2O4 electrode exhibited a capacity retention rate of 54%, whereas the P-NiCo-LDH electrode showed a capacity retention rate of 57%. KCI Citation Count: 0