해수 기반 전기화학소자의 안정적인 전극을 위한 내염소층 설계

• Published in: Biuletyn Uniejowski Vol. 57; no. 4; pp. 325 - 330
• Main Authors: 김수연(Suyeon Kim), Aye Myint Myat Kyaw, 김채언(Chaeun Kim), 장예원(Yewon Jang), 한유리(Youri Han), Li Oi Lun
• Format: Journal Article
• Language: Korean
• Published: 한국표면공학회 2024
• Subjects: 기계공학; N,S doping; Carbon; Chloride evolution reaction; Corrosion-resistant layer; Seawater
• ISSN: 1225-8024; 2299-8403; 2288-8403
• DOI: 10.5695/JSSE.2024.57.4.325

When seawater is used in electrochemical devices, issues arise such as the adsorption of chloride ions blocking the active sites for Oxygen reduction reactions (ORR) in seawater batteries, and the occurrence of Chlorine evolution reactions (ClER) in seawater electrolysis due to chloride anions (Cl-) competing with OH- for catalytic active sites, potentially slowing down Oxygen evolution reactions (OER). Consequently, the performance of components used in seawater battery and seawater electrolysis may deteriorate. Therefore, conventional alloys are often used by coating or plating methods to minimize corrosion, albeit at the cost of reducing electrical conductivity. This study thus designed a corrosion-resistant layer by doping carbon with Nitrogen (N) and Sulfur (S) to maintain electrical conductivity while preventing corrosion. Optimal N,S doping ratios were developed, with corrosion experiments confirming that N,S (10:90) carbon exhibited the best corrosion resistance performance.