プロピレンカーボネート/プロピレンオキシド共重合体電解質のイオン伝導特性
固体高分子電解質は，安全性が高く加工性に優れた次世代のイオニクス材料として期待されているが，実用化に向けてはさらなる改善が必要である．脂肪族ポリカーボネートは，主鎖中のカーボネート基による高い塩溶解性とカチオンとの適度な相互作用により，イオン伝導度の向上が見込まれる．本研究では，ポリカーボネート型電解質のイオン伝導度に対する主鎖構造の影響について，主鎖中のエーテル結合の割合が15，50，77%のランダム共重合体およびプロピレンオキシド56%とポリプロピレンカーボネート44%のブロック共重合体を用いて調査した．ポリプロピレンカーボネートの主鎖構造に柔軟なエーテル鎖を導入することで，ポリカーボネー...
Saved in:
| Published in | Kōbunshi ronbunshū (Tokyo) Vol. 74; no. 6; pp. 577 - 583 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | Japanese |
| Published |
Tokyo
公益社団法人 高分子学会
01.01.2017
Japan Science and Technology Agency |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0386-2186 1881-5685 |
| DOI | 10.1295/koron.2017-0051 |
Cover
| Abstract | 固体高分子電解質は，安全性が高く加工性に優れた次世代のイオニクス材料として期待されているが，実用化に向けてはさらなる改善が必要である．脂肪族ポリカーボネートは，主鎖中のカーボネート基による高い塩溶解性とカチオンとの適度な相互作用により，イオン伝導度の向上が見込まれる．本研究では，ポリカーボネート型電解質のイオン伝導度に対する主鎖構造の影響について，主鎖中のエーテル結合の割合が15，50，77%のランダム共重合体およびプロピレンオキシド56%とポリプロピレンカーボネート44%のブロック共重合体を用いて調査した．ポリプロピレンカーボネートの主鎖構造に柔軟なエーテル鎖を導入することで，ポリカーボネート単体よりもTgが低下し，イオン電導度は向上した． |
|---|---|
| AbstractList | 固体高分子電解質は，安全性が高く加工性に優れた次世代のイオニクス材料として期待されているが，実用化に向けてはさらなる改善が必要である．脂肪族ポリカーボネートは，主鎖中のカーボネート基による高い塩溶解性とカチオンとの適度な相互作用により，イオン伝導度の向上が見込まれる．本研究では，ポリカーボネート型電解質のイオン伝導度に対する主鎖構造の影響について，主鎖中のエーテル結合の割合が15，50，77%のランダム共重合体およびプロピレンオキシド56%とポリプロピレンカーボネート44%のブロック共重合体を用いて調査した．ポリプロピレンカーボネートの主鎖構造に柔軟なエーテル鎖を導入することで，ポリカーボネート単体よりもTgが低下し，イオン電導度は向上した． Solid polymer electrolytes (SPEs) have been expected as solid-state electrolytes in electrochemical applications. However, ionic conductivity of SPEs are lower than that of common liquid and gel electrolytes. In this study, random and block copolymers were synthesized from CO2 and propylene oxide, and the ion conductive properties of block copolymers that consist of a polypropylene oxide central block connected to poly(propylene carbonate) (PPC) segments at both ends were investigated. We used three types of random copolymers containing different amount of ether units and one block copolymer. SPE samples were prepared by adding 20–100 mol% LiTFSI to the polymers. All copolymers showed a lower glass transition temperature and higher ion conductivity than those of PPC electrolytes. On the other hand, the random copolymers showed a lower ion conductivity than that of the block copolymer. |
| Author | 古賀, 舞都 橋本, 啓輔 富永, 洋一 |
| Author_xml | – sequence: 1 fullname: 古賀, 舞都 organization: 東京農工大学大学院 生物システム応用科学府 – sequence: 1 fullname: 富永, 洋一 organization: 東京農工大学大学院 生物システム応用科学府 – sequence: 1 fullname: 橋本, 啓輔 organization: 東京農工大学大学院 生物システム応用科学府 |
| BookMark | eNplkE1LAkEYx4cwyMxzH6Dz6szOvsweQ-wFhC7eh9l1t9xs13b10K12iPRgBAUdqlOBYBmFh4js04yWfot2Nbp0ef4P_H88D_yWQcrzPRuAVQRzSDbU_L4f-F5OhkiXIFTRAkgjQpCkakRNgTTERJNkRLQlkA3DqhkjBkQG1NLAFfxa8L7gV4I_CT4Q0aPgQ8FvBe_Mllb-H9ETUV9Eb4K3x6ev07PO-KI1-ryc3nxMuveTQU-cPIvoIcH4YDS8G7-cf7ffv467K2DRYbXQzv5mBpQ3iuXCllTa2dwurJckVyaKIWGimDK2TMiQYUG9gkzGEDYdCGWbMM1WmUaYrlgVTJBm6MghOoZIJU5SmgRnwNr8bD3wD5t22KCu3wy8-CON_SiqoRPViKninHLDBtu1aT2oHrDgiLKgUbVqNp0JpbpCtWQkYmki9q-39lhAXYZ_ALQVl34 |
| ContentType | Journal Article |
| Copyright | 2017 公益社団法人 高分子学会 Copyright Japan Science and Technology Agency 2017 |
| Copyright_xml | – notice: 2017 公益社団法人 高分子学会 – notice: Copyright Japan Science and Technology Agency 2017 |
| DBID | 7SR 8FD JG9 |
| DOI | 10.1295/koron.2017-0051 |
| DatabaseName | Engineered Materials Abstracts Technology Research Database Materials Research Database |
| DatabaseTitle | Materials Research Database Technology Research Database Engineered Materials Abstracts |
| DatabaseTitleList | Materials Research Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| EISSN | 1881-5685 |
| EndPage | 583 |
| ExternalDocumentID | article_koron_74_6_74_2017_0051_article_char_ja |
| GroupedDBID | 5GY ACGFS ACIWK AENEX ALMA_UNASSIGNED_HOLDINGS CS3 DU5 JSF KQ8 RJT 7SR 8FD JG9 |
| ID | FETCH-LOGICAL-j2849-384b23cb0a19c07d1baa13bf002e8a6e5a68a74cd3816971f8730158f8a6eb83 |
| ISSN | 0386-2186 |
| IngestDate | Mon Jun 30 04:07:17 EDT 2025 Wed Sep 03 06:29:00 EDT 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 6 |
| Language | Japanese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-j2849-384b23cb0a19c07d1baa13bf002e8a6e5a68a74cd3816971f8730158f8a6eb83 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 |
| OpenAccessLink | https://www.jstage.jst.go.jp/article/koron/74/6/74_2017-0051/_article/-char/ja |
| PQID | 2014597859 |
| PQPubID | 2048501 |
| PageCount | 7 |
| ParticipantIDs | proquest_journals_2014597859 jstage_primary_article_koron_74_6_74_2017_0051_article_char_ja |
| PublicationCentury | 2000 |
| PublicationDate | 20170101 |
| PublicationDateYYYYMMDD | 2017-01-01 |
| PublicationDate_xml | – month: 01 year: 2017 text: 20170101 day: 01 |
| PublicationDecade | 2010 |
| PublicationPlace | Tokyo |
| PublicationPlace_xml | – name: Tokyo |
| PublicationTitle | Kōbunshi ronbunshū (Tokyo) |
| PublicationTitleAlternate | 高分子論文集 |
| PublicationYear | 2017 |
| Publisher | 公益社団法人 高分子学会 Japan Science and Technology Agency |
| Publisher_xml | – name: 公益社団法人 高分子学会 – name: Japan Science and Technology Agency |
| References | 18) X. Wei and D. F. Shriver, Chem. Mater., 10, 2307 (1998). 19) Y. Saito, K. Hirai, H. Katayama, T. Abe, M. Yokoe, K. Aoi, and M. Okada, Macromolecules., 38, 6485 (2005). 1) J.-M. Tarascon and M. B. Armand, Nature., 414, 359 (2001). 3) M. B. Armand, J. M. Chagagno, and M. T. Duclot, “Fast Ion Transport in Solids”, P. Vashishta, J. N. Mumdy, and G. K. Shennoy eds., Elsevier, Amsterdam (1979), p. 131. 14) B. Sun, J. Mindemark, K. Edström, and D. Brandell, Solid State Ionics, 262, 738 (2014). 9) F. M. Gray, “Solid Polymer Electrolytes: Fundamentals and Technological Applications”, VCH Publishers, Weinheim, Germany (1991), p. 245. 15) Y. Tominaga, K. Yamazaki, and V. Nanthana, J. Electrochem. Soc., 162, A3133 (2015). 10) A. Nishimoto, K. Agehara, N. Furuya, T. Watanabe, and M. Watanabe, Macromolecules, 32, 1541 (1999). 4) S. Takeoka, H. Ohno, and E. Tsuchida, Polym. Adv. Technol., 4, 53 (1993). 16) J. Motomatsu, H. Kodama, T. Furukawa, and Y. Tominaga, Macromol. Chem. Phys., 216, 1660 (2015). 22) L. Gu, Y. Gao, Y. Qin, X. Chen, X. Wang, and F. Wang, J. Polym. Sci., Part A: Polym. Chem., 51, 282 (2013). 12) Y. Tominaga, T. Shimomura, and M. Nakamura, Polymer, 51, 4295 (2010). 23) C. T. Cohen, T. Chu, and G. W. Coates, J. Am. Chem. Soc., 127, 10869 (2005). 5) S. Sylla, J. Y. Sanchez, and M. Armand, Electrochim. Acta, 37, 1699 (1992). 17) T. Morioka, K. Ota, and Y. Tominaga, Polymer, 84, 21 (2016). 8) Y. Tominaga, Y. Izumi, G.-H. Kwak, S. Asai, and M. Sumita, Macromolecules, 36, 8766 (2003). 6) F. Croce, G. B. Appetecchi, L. Persi, and B. Scrosati, Nature, 394, 456 (1998). 7) J. Hassoun, S. Panero, P. Reale, and B. Scrosati, Adv. Mater., 21, 4807 (2009). 21) T. Morioka, K. Nakano, and Y. Tominaga, Macromol. Rapid Commun., 38, 1600652 (2017). 2) B. Scrosati and J. Garche, J. Power Sources, 195, 2419 (2010). 13) Y. Tominaga, V. Nanthana, and D. Tohyama, Polym. J., 44, 1155 (2012). 24) V. Nanthana and Y. Tominaga, Kobunshi Ronbunshu, 70, 23 (2013). 11) M. Watanabe and N. Ogata, “Polymer Electrolyte Reviews 1”, J. R. MacCallum and C. A. Vincent eds., Elsevier, London (1987), Chapter 3, p. 39. 20) Y. Tominaga and K. Yamazaki, Chem. Commun., 50, 4448 (2014). 25) K. Kimura, J. Motomatsu, and Y. Tominaga, J. Phys. Chem. C, 120, 12385 (2016). |
| References_xml | – reference: 18) X. Wei and D. F. Shriver, Chem. Mater., 10, 2307 (1998). – reference: 24) V. Nanthana and Y. Tominaga, Kobunshi Ronbunshu, 70, 23 (2013). – reference: 5) S. Sylla, J. Y. Sanchez, and M. Armand, Electrochim. Acta, 37, 1699 (1992). – reference: 13) Y. Tominaga, V. Nanthana, and D. Tohyama, Polym. J., 44, 1155 (2012). – reference: 11) M. Watanabe and N. Ogata, “Polymer Electrolyte Reviews 1”, J. R. MacCallum and C. A. Vincent eds., Elsevier, London (1987), Chapter 3, p. 39. – reference: 21) T. Morioka, K. Nakano, and Y. Tominaga, Macromol. Rapid Commun., 38, 1600652 (2017). – reference: 22) L. Gu, Y. Gao, Y. Qin, X. Chen, X. Wang, and F. Wang, J. Polym. Sci., Part A: Polym. Chem., 51, 282 (2013). – reference: 7) J. Hassoun, S. Panero, P. Reale, and B. Scrosati, Adv. Mater., 21, 4807 (2009). – reference: 8) Y. Tominaga, Y. Izumi, G.-H. Kwak, S. Asai, and M. Sumita, Macromolecules, 36, 8766 (2003). – reference: 1) J.-M. Tarascon and M. B. Armand, Nature., 414, 359 (2001). – reference: 6) F. Croce, G. B. Appetecchi, L. Persi, and B. Scrosati, Nature, 394, 456 (1998). – reference: 25) K. Kimura, J. Motomatsu, and Y. Tominaga, J. Phys. Chem. C, 120, 12385 (2016). – reference: 16) J. Motomatsu, H. Kodama, T. Furukawa, and Y. Tominaga, Macromol. Chem. Phys., 216, 1660 (2015). – reference: 17) T. Morioka, K. Ota, and Y. Tominaga, Polymer, 84, 21 (2016). – reference: 4) S. Takeoka, H. Ohno, and E. Tsuchida, Polym. Adv. Technol., 4, 53 (1993). – reference: 14) B. Sun, J. Mindemark, K. Edström, and D. Brandell, Solid State Ionics, 262, 738 (2014). – reference: 23) C. T. Cohen, T. Chu, and G. W. Coates, J. Am. Chem. Soc., 127, 10869 (2005). – reference: 20) Y. Tominaga and K. Yamazaki, Chem. Commun., 50, 4448 (2014). – reference: 15) Y. Tominaga, K. Yamazaki, and V. Nanthana, J. Electrochem. Soc., 162, A3133 (2015). – reference: 9) F. M. Gray, “Solid Polymer Electrolytes: Fundamentals and Technological Applications”, VCH Publishers, Weinheim, Germany (1991), p. 245. – reference: 2) B. Scrosati and J. Garche, J. Power Sources, 195, 2419 (2010). – reference: 10) A. Nishimoto, K. Agehara, N. Furuya, T. Watanabe, and M. Watanabe, Macromolecules, 32, 1541 (1999). – reference: 3) M. B. Armand, J. M. Chagagno, and M. T. Duclot, “Fast Ion Transport in Solids”, P. Vashishta, J. N. Mumdy, and G. K. Shennoy eds., Elsevier, Amsterdam (1979), p. 131. – reference: 19) Y. Saito, K. Hirai, H. Katayama, T. Abe, M. Yokoe, K. Aoi, and M. Okada, Macromolecules., 38, 6485 (2005). – reference: 12) Y. Tominaga, T. Shimomura, and M. Nakamura, Polymer, 51, 4295 (2010). |
| SSID | ssib005901906 ssib000972329 ssj0059176 ssib014653950 ssib053392992 |
| Score | 2.1268065 |
| Snippet | 固体高分子電解質は，安全性が高く加工性に優れた次世代のイオニクス材料として期待されているが，実用化に向けてはさらなる改善が必要である．脂肪... Solid polymer electrolytes (SPEs) have been expected as solid-state electrolytes in electrochemical applications. However, ionic conductivity of SPEs are lower... |
| SourceID | proquest jstage |
| SourceType | Aggregation Database Publisher |
| StartPage | 577 |
| SubjectTerms | Block copolymers Carbon dioxide Chemical synthesis Copolymers Electrolytes Glass transition temperature Ion currents Molten salt electrolytes Polypropylene glycol Propylene Propylene oxide Solid electrolytes |
| Title | プロピレンカーボネート/プロピレンオキシド共重合体電解質のイオン伝導特性 |
| URI | https://www.jstage.jst.go.jp/article/koron/74/6/74_2017-0051/_article/-char/ja https://www.proquest.com/docview/2014597859 |
| Volume | 74 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| ispartofPNX | 高分子論文集, 2017/11/25, Vol.74(6), pp.577-583 |
| journalDatabaseRights | – providerCode: PRVAFT databaseName: Open Access Digital Library customDbUrl: eissn: 1881-5685 dateEnd: 99991231 omitProxy: true ssIdentifier: ssj0059176 issn: 0386-2186 databaseCode: KQ8 dateStart: 19740101 isFulltext: true titleUrlDefault: http://grweb.coalliance.org/oadl/oadl.html providerName: Colorado Alliance of Research Libraries |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3NT9RAFG8AL3owfkYUDQfHCylstzPtzMWk3V3ke2MsCZ6adj-UJWER2EQ96TZGOGBMNPGgnjQhQTEaDsaIf01B4b_wvU67W1hjlMvkZb7edKYz7zcf7z1FucoyVVYueUytCoBv1KBCFdkyU70y1_1KRlQy0UZxcsoYmaZjM2ymq_t-6tVSY9kfLD38o17JUUYV4mBcUUv2P0a2VSlEAA3jCyGMMIT_NMakoBOuE2HGhJVPYmgSk4sJW4-ILLHsJCZJEgnB84eTOL7dPxIXKyHyMWEnxbkgBUY4I7ZGCoJwM-LLiMgguwIldp4IHZOETWxoLSeWSSwdCag_rlkjViFhQQ8ylc2g-BUiqtmGmiGziaxt4G7g8w7LTOPy8TrJ5QinfgOfrw0s1ucjqiFjEYY79bkH9dS5yXjxhiWVnWBNbE0O69bI6GTRKUqVp9mlxlxr4jjFydEpSxa6XZ8t3Z1Nn7ho5qETlzFAMe2lF6832rcgA1akMZtaxHVuqOj3S8pbKWQ411RmSFdFiRSSvori2ZYWKUy6uekQdVmBVkHm0M7FoGxlJjbde8Co-FTRHZ6emHCdwoxzbeGeiv7W8F1C7HymWzmWBXmITk_Gb6aAOTqjSwFn1FBO-QXQ0CqfaN-Hw54BYLZoGW5jQjPlK4H462OjWtDmoUMtBuRXg33QnU4wFCE855RyMt6a9Vtynp1WumreGeVEymDnWaUWBq_CYDMMXobBxzDYCpsfwmA7DN6EwVpErAx15NgIm5th82sYrO4--bL_dG33-crOjxf7r7_vrb_b29oIH38Km-8xW7C1s_129_OzX6vffj5aP6c4wwUnN6LG3krUGkA8oerwj2b1kp_xNFHKmGXN9zxN96sAOSrcMyrMM7hn0lIZr-qFqVU5ClfGq5joc_280jNfn69cUPorgmrZcplyKIneLYTPDWpSAPecMlHivcp12WXugrRI48YrkBv1rWtS18AA-9jFPm6loyanW_N6lb6kq914OVvC3FC7yZm4-PfkS8rx9qzoU3qWFxuVy4DMl_0r0U_0G8nl0v8 |
| linkProvider | Colorado Alliance of Research Libraries |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E3%83%97%E3%83%AD%E3%83%94%E3%83%AC%E3%83%B3%E3%82%AB%E3%83%BC%E3%83%9C%E3%83%8D%E3%83%BC%E3%83%88%2F%E3%83%97%E3%83%AD%E3%83%94%E3%83%AC%E3%83%B3%E3%82%AA%E3%82%AD%E3%82%B7%E3%83%89%E5%85%B1%E9%87%8D%E5%90%88%E4%BD%93%E9%9B%BB%E8%A7%A3%E8%B3%AA%E3%81%AE%E3%82%A4%E3%82%AA%E3%83%B3%E4%BC%9D%E5%B0%8E%E7%89%B9%E6%80%A7&rft.jtitle=Ko%CC%84bunshi+ronbunshu%CC%84+%28Tokyo%29&rft.au=KOGA%2C+Maito&rft.au=HASHIMOTO%2C+Keisuke&rft.au=TOMINAGA%2C+Yoichi&rft.date=2017-01-01&rft.pub=Japan+Science+and+Technology+Agency&rft.issn=0386-2186&rft.eissn=1881-5685&rft.volume=74&rft.issue=6&rft.spage=577&rft_id=info:doi/10.1295%2Fkoron.2017-0051&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0386-2186&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0386-2186&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0386-2186&client=summon |