銀塩写真感光材料における光電変換過程の効率向上と有機デバイスへの展開

銀塩写真感光材料の感光過程は，光吸収による励起子の生成，励起子の解離（光電変換）による電子と正孔の生成および生成した電子と格子間銀イオンによる写真現象（潜像形成）の実現からなる．これらの過程の効率の分析と向上の方法を紹介し，それらの知見を色素増感太陽電池，有機薄膜太陽電池，有機撮像素子などの有機デバイスへと展開した．...

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Published in日本写真学会誌 Vol. 74; no. 6; pp. 290 - 301
Main Author 谷, 忠昭
Format Journal Article
LanguageJapanese
Published 社団法人 日本写真学会 2011
Subjects
カラーフィルム
光吸収
光電変換
移動度
色素増感
Online AccessGet full text
ISSN0369-5662
1884-5932
DOI10.11454/photogrst.74.290

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Abstract 銀塩写真感光材料の感光過程は，光吸収による励起子の生成，励起子の解離（光電変換）による電子と正孔の生成および生成した電子と格子間銀イオンによる写真現象（潜像形成）の実現からなる．これらの過程の効率の分析と向上の方法を紹介し，それらの知見を色素増感太陽電池，有機薄膜太陽電池，有機撮像素子などの有機デバイスへと展開した．
AbstractList 銀塩写真感光材料の感光過程は，光吸収による励起子の生成，励起子の解離（光電変換）による電子と正孔の生成および生成した電子と格子間銀イオンによる写真現象（潜像形成）の実現からなる．これらの過程の効率の分析と向上の方法を紹介し，それらの知見を色素増感太陽電池，有機薄膜太陽電池，有機撮像素子などの有機デバイスへと展開した．
Author 谷, 忠昭
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4) J. T. Kofron, R. E. Booms, J. Soc. Photogr. Sci. Technol., 49, 15 (1986).
27) A. Hirsch, "The Chemistry of the Fullerenes", Georg Thieme Verlag, Stuttgart, New York, 1994.
9) T. Tani, J. Imaging Sci. Technol., 51, 110 (2007).
30) S. Guenes, H. Neugebauer, N. S. Sariciftci, Chem. Rev., 107, 1324 (2007).
32) H. Kanzaki, S. Sakuragi, J. Phys. Soc. Jpn., 29, 924 (1970).
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16) 相原　聡，日本写真学会誌，69(5), 320 (2006).
31) 大北英生，第8回日本写真学会光機能性材料セミナー，平成23年6月30日，日本印刷会館，東京
37) I. G. Hill, A. Kahn, Z. G. Soos, and R. A. Pascal, Jr., Chem. Phys. Lett., 327, 181 (2000).
42) R. A. Marcus, Discuss. Faraday Soc., 29, 21 (1960).
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18) M. Ihama, M. Hayashi, Y. Maehara, T. Mitsui, S. Takada, Proc. SPIE, 6656, 66560A (2007).
24) P. Peumans, A. Yakimov, S. R. Forrest, J. Appl. Phys., 93, 3693 (2003).
48) P. B. Gilman, Jr., Photogr. Sci. Eng., 18, 418 (1974).
51) T. Tani, J. Imaging Sci., 30, 41 (1986).
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6) G. R. Bird, Photogr. Sci. Eng., 18, 562 (1974).
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7) J. C. Marchant, in "Progress in Basic Principles of Imaging Systems", F. Granzer, E. Moisar, eds., Friedr. Vieweg & Sohn, Braunschweig/Wiesbaden, 1986, p.9.
57) R. J. Deri, J. P. Spoonhower, Appl. Phys. Lett., 43, 651 (1983).
29) M. M. Wienk, J. M. Kroon, J. H. Verhees, J. Knol, J. C. Hummelen, P. A. van Hal, R. A. Janssen, Angew. Chem. Intern. Ed., 42, 3371 (2003).
23) C. W. Tang, Appl. Phys. Lett., 48, 183 (1986).
36) 谷　忠昭，“有機半導体の物性の評価と理論およびデバイス応用”，情報機構，東京，2011.
28) B. Maennig, M. Pfeiffer, A. Nollau, X. Zhou, K. Leo, Phys. Rev. B, 64, 195208 (2001).
44) M. T. Spitler, A. Ehert, R. Kietzmann, F. Willig, J. Phys. Chem. B, 101, 2552 (1997).
53) J. F. Hamilton, L. E. Brady, J. Appl. Phys., 30, 1893 (1959).
34) V. I. Saunders, R. W. Tyler, W. West, Photogr. Sci. Eng., 16, 87 (1972).
49) I. R. Gould, J. R. Lenhard, A. A. Muenter, S. A. Godleski, S. Y. Farid, J. Am. Chem. Soc., 122, 11934 (2000).
3) Anonymous, Res. Disc. (Item 22534) 225, 20 (Jan. 1983).
35) V. I. Arkhipov, H. Baessler, in "Physics of Organic Semiconductors", W. Bruetting, ed., Wiley-VCH, Verlag GmbH & Co., KgaA, Weinheim, 2005, pp. 183-233.
56) L. M. Kellogg, Photogr. Sci. Eng., 18, 378 (1974).
2) Tadaaki Tani, "Photographic Science: Advances in Nanoparticles, J-Aggregates, Dye Sensitization, and Organic Devices", Oxford University Press, Oxford, 2011.
8) Y. Okamoto, Nachr. Wiss. Goettingen, Math.-Physik. Kl. IIa, Math. -Physik.- Chem. Abt., 275 (No. 14, 1956).
17) S. Takada, M. Ihama, M. Inuiya, Proc. SPIE, 6068, 60680A (2006).
47) K. Hashimoto, M. Hiramoto, A. B. P. Lever, T. Sakata, J. Phys. Chem., 92, 1016 (1988).
12) D. E. Hill, Phys. Rev., 133, A866 (1964).
43) J. Spence, B. H. Carroll, J. Phys. Colloid Chem., 52, 1090 (1948).
55) L. M. Kellogg, N. B. Liebert, T. H. James, Photogr. Sci. Eng., 16, 115 (1972).
38) T. Tani, T. Suzumoto, K. Ohzeki, J. Phys. Chem., 94, 1298 (1990).
13) H. C. Casey, Jr., D. D. Shell, K. W. Wecht, J. Appl. Phys., 46, 250 (1975).
References_xml – reference: 51) T. Tani, J. Imaging Sci., 30, 41 (1986).
– reference: 11) H. R. Phillip, E. A. Taft, Phys. Rev. Lett., 8, 13 (1962).
– reference: 37) I. G. Hill, A. Kahn, Z. G. Soos, and R. A. Pascal, Jr., Chem. Phys. Lett., 327, 181 (2000).
– reference: 29) M. M. Wienk, J. M. Kroon, J. H. Verhees, J. Knol, J. C. Hummelen, P. A. van Hal, R. A. Janssen, Angew. Chem. Intern. Ed., 42, 3371 (2003).
– reference: 42) R. A. Marcus, Discuss. Faraday Soc., 29, 21 (1960).
– reference: 38) T. Tani, T. Suzumoto, K. Ohzeki, J. Phys. Chem., 94, 1298 (1990).
– reference: 54) E. V. Baranov, I. A. Akimov, Dokl. Akad. Nauk. SSSR, 154, 7 (1964).
– reference: 48) P. B. Gilman, Jr., Photogr. Sci. Eng., 18, 418 (1974).
– reference: 1) Tadaaki Tani, "Photographic Sensitivity: Theory and Mechanisms", Oxford University Press, New York, Oxford, 1995.
– reference: 59) L. M. Kellogg, J. Hodes, J. Muenter, "Measurement of Photocarrier Decay Times in Silver Halide Emulsion Grains Using Radiofrequency Techniques", in Proc. Intern. East-West Symposium, IS&T, Springfield, VA, 1988, C11-15.
– reference: 5) G. R. Bird, R. C. Jones, A. E. Ames, Appl. Optics, 8, 2389 (1969).
– reference: 18) M. Ihama, M. Hayashi, Y. Maehara, T. Mitsui, S. Takada, Proc. SPIE, 6656, 66560A (2007).
– reference: 26) B. P. Rand, J. Xue, F. Yang, S. R. Forrest, Appl. Phys. Lett., 87, 233508 (2005).
– reference: 16) 相原　聡，日本写真学会誌，69(5), 320 (2006).
– reference: 17) S. Takada, M. Ihama, M. Inuiya, Proc. SPIE, 6068, 60680A (2006).
– reference: 28) B. Maennig, M. Pfeiffer, A. Nollau, X. Zhou, K. Leo, Phys. Rev. B, 64, 195208 (2001).
– reference: 52) J. R. Hayes, W. Shockley, Phys. Rev., 82, 935 (1951).
– reference: 10) W. C. Dash, R. Newman, Phys. Rev., 99, 1151 (1955).
– reference: 57) R. J. Deri, J. P. Spoonhower, Appl. Phys. Lett., 43, 651 (1983).
– reference: 20) A. Hagfeldt, M. Graetzel, Chem. Rev., 95, 49 (1995).
– reference: 47) K. Hashimoto, M. Hiramoto, A. B. P. Lever, T. Sakata, J. Phys. Chem., 92, 1016 (1988).
– reference: 63) R. K. Ahrenkiel, Phys. Rev., 180, 859 (1969).
– reference: 8) Y. Okamoto, Nachr. Wiss. Goettingen, Math.-Physik. Kl. IIa, Math. -Physik.- Chem. Abt., 275 (No. 14, 1956).
– reference: 46) K. Hashimoto, M. Hiramoto, T. Sakata, Chem. Phys. Lett., 148, 215 (1988).
– reference: 3) Anonymous, Res. Disc. (Item 22534) 225, 20 (Jan. 1983).
– reference: 14) S. Aihara, Y. Hirano, T. Tajima, K. Tanioka, M. Abe, N. Saito, Appl. Phys. Lett., 82, 511 (2003).
– reference: 35) V. I. Arkhipov, H. Baessler, in "Physics of Organic Semiconductors", W. Bruetting, ed., Wiley-VCH, Verlag GmbH & Co., KgaA, Weinheim, 2005, pp. 183-233.
– reference: 12) D. E. Hill, Phys. Rev., 133, A866 (1964).
– reference: 45) F. Willig, M. T. Spitler, J. Imaging Sci. Technol., 41, 272 (1997).
– reference: 62) J. M. Warman, A. M. Van De Croats, Mol. Cryst. Liq. Cryst., 396, 41 (2005).
– reference: 50) J. M. Harbison, H. E. Spencer, in "The Theory of the Photographic Process", 4 th ed., T. H. James, eds., Macmillan, New York, 1977, p. 152.
– reference: 60) K. Hosoi, A. Hirano, T. Tani, J. Imaging Sci. Technol., 46, 76 (2002).
– reference: 53) J. F. Hamilton, L. E. Brady, J. Appl. Phys., 30, 1893 (1959).
– reference: 43) J. Spence, B. H. Carroll, J. Phys. Colloid Chem., 52, 1090 (1948).
– reference: 36) 谷　忠昭，“有機半導体の物性の評価と理論およびデバイス応用”，情報機構，東京，2011.
– reference: 2) Tadaaki Tani, "Photographic Science: Advances in Nanoparticles, J-Aggregates, Dye Sensitization, and Organic Devices", Oxford University Press, Oxford, 2011.
– reference: 19) B. O'Regan, M. Graetzel, Nature, 353, 737 (1991).
– reference: 40) W. West, B. H. Carroll, J. Chem. Phys., 15, 529 (1947).
– reference: 30) S. Guenes, H. Neugebauer, N. S. Sariciftci, Chem. Rev., 107, 1324 (2007).
– reference: 4) J. T. Kofron, R. E. Booms, J. Soc. Photogr. Sci. Technol., 49, 15 (1986).
– reference: 7) J. C. Marchant, in "Progress in Basic Principles of Imaging Systems", F. Granzer, E. Moisar, eds., Friedr. Vieweg & Sohn, Braunschweig/Wiesbaden, 1986, p.9.
– reference: 33) M. Ueta, H. Kanzaki, K. Kobayashi, Y. Toyozawa, E. Hanamura, Excitonic Processes in Solids, Springer, New York, 1986, Chapter 6.
– reference: 49) I. R. Gould, J. R. Lenhard, A. A. Muenter, S. A. Godleski, S. Y. Farid, J. Am. Chem. Soc., 122, 11934 (2000).
– reference: 56) L. M. Kellogg, Photogr. Sci. Eng., 18, 378 (1974).
– reference: 15) S. Aihara, K. Miyakawa, Y. Ohkawa, T. Matsubara, T. Takahata, S. Suzuki, M. Kubota, K. Tanioka, N. Kamata, D. Terunuma, Jpn. J. Appl. Phys., 44, 3743 (2005).
– reference: 24) P. Peumans, A. Yakimov, S. R. Forrest, J. Appl. Phys., 93, 3693 (2003).
– reference: 34) V. I. Saunders, R. W. Tyler, W. West, Photogr. Sci. Eng., 16, 87 (1972).
– reference: 31) 大北英生，第8回日本写真学会光機能性材料セミナー，平成23年6月30日，日本印刷会館，東京．
– reference: 6) G. R. Bird, Photogr. Sci. Eng., 18, 562 (1974).
– reference: 21) M. Graetzel, Nature, 414, 338 (2001).
– reference: 61) 平本昌宏，坂上嘉孝，横山正明，日本化学会誌，1180 (1992).
– reference: 13) H. C. Casey, Jr., D. D. Shell, K. W. Wecht, J. Appl. Phys., 46, 250 (1975).
– reference: 55) L. M. Kellogg, N. B. Liebert, T. H. James, Photogr. Sci. Eng., 16, 115 (1972).
– reference: 44) M. T. Spitler, A. Ehert, R. Kietzmann, F. Willig, J. Phys. Chem. B, 101, 2552 (1997).
– reference: 41) W. West, B. H. Carroll, J. Chem. Phys., 19, 417 (1951).
– reference: 25) G. Yu, J. Gao, J. C. Hummelen, F. Wudl, A. J. Heeger, Science, 270, 1789 (1995).
– reference: 58) D. J. Deri, J. P. Spoonhower, J. Appl. Phys., 57, 2806 (1985).
– reference: 27) A. Hirsch, "The Chemistry of the Fullerenes", Georg Thieme Verlag, Stuttgart, New York, 1994.
– reference: 32) H. Kanzaki, S. Sakuragi, J. Phys. Soc. Jpn., 29, 924 (1970).
– reference: 9) T. Tani, J. Imaging Sci. Technol., 51, 110 (2007).
– reference: 22) S. Honda, T. Nogami, H. Ohkita, H. Benten, S. Ito, Appl. Mater. Interfaces, 1, 804 (2009).
– reference: 39) M. Scharber, D. Muelbacher, M. Koppe, P. Denk, C. Waldauf, A. Heeger, C. Brabec, Adv. Mater., 18, 789 (2006).
– reference: 23) C. W. Tang, Appl. Phys. Lett., 48, 183 (1986).
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Snippet 銀塩写真感光材料の感光過程は，光吸収による励起子の生成，励起子の解離（光電変換）による電子と正孔の生成および生成した電子と格子間銀イオンによる写真現象（潜像形...
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SubjectTerms カラーフィルム
光吸収
光電変換
移動度
色素増感
Title 銀塩写真感光材料における光電変換過程の効率向上と有機デバイスへの展開
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