Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO 2
An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO 2 . β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of car...
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| Published in | RSC advances Vol. 9; no. 56; pp. 32628 - 32633 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
15.10.2019
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| Online Access | Get full text |
| ISSN | 2046-2069 2046-2069 |
| DOI | 10.1039/C9RA05253D |
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| Abstract | An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO
2
. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides. |
|---|---|
| AbstractList | An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO
. β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides. An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO 2 . β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides. |
| Author | Guan, Ye-Bin Wang, Huan Wang, Hui Zhao, Ying-Guo Lan, Yang-Chun Lu, Jia-Xing Wu, La-Xia |
| Author_xml | – sequence: 1 givenname: La-Xia surname: Wu fullname: Wu, La-Xia organization: AnHui Province Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, China – sequence: 2 givenname: Ying-Guo surname: Zhao fullname: Zhao, Ying-Guo organization: AnHui Province Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, China – sequence: 3 givenname: Ye-Bin surname: Guan fullname: Guan, Ye-Bin organization: AnHui Province Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, China – sequence: 4 givenname: Hui surname: Wang fullname: Wang, Hui organization: School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China – sequence: 5 givenname: Yang-Chun surname: Lan fullname: Lan, Yang-Chun organization: Department of Electrical and Electronic Engineering, Southern University of Science and Technology, ShenZhen 518055, China – sequence: 6 givenname: Huan surname: Wang fullname: Wang, Huan organization: School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China – sequence: 7 givenname: Jia-Xing orcidid: 0000-0001-9239-9888 surname: Lu fullname: Lu, Jia-Xing organization: School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35529726$$D View this record in MEDLINE/PubMed |
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| Snippet | An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO
2
.... An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO .... |
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| Title | Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO 2 |
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