Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO 2

An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO 2 . β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of car...

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Published inRSC advances Vol. 9; no. 56; pp. 32628 - 32633
Main Authors Wu, La-Xia, Zhao, Ying-Guo, Guan, Ye-Bin, Wang, Hui, Lan, Yang-Chun, Wang, Huan, Lu, Jia-Xing
Format Journal Article
LanguageEnglish
Published England 15.10.2019
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ISSN2046-2069
2046-2069
DOI10.1039/C9RA05253D

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Summary:An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO 2 . β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides.
ISSN:2046-2069
2046-2069
DOI:10.1039/C9RA05253D