脱硫石膏对土壤磷流失的阻控效应及机制试验
研究脱硫石膏(flue-gas desulfurization gypsum,FGDG)对土壤磷流失的阻控效果,既有利于开拓FGDG资源化利用新途径,又有助于丰富农业面源磷流失控制工程技术。借助土柱淋溶试验和人工边坡降雨侵蚀模拟试验,针对上海某火电厂的FGDG,系统研究不同质量配比(0、1%、2.5%和5%)的FGDG对农田土壤的固磷效果及机理。结果表明:1)FGDG的Ca2+将溶解态P转化成难溶态P,并将土壤无机磷中的Ca2-P、Al-P转化成Ca8-P和Ca10-P,有效控制溶解态磷(total dissolved phosphorus,TDP)直接流失,与对照组相比,施加FGDG对淋洗土...
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| Published in | 农业工程学报 Vol. 33; no. 3; pp. 148 - 154 |
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| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
上海市环境科学研究院,上海,200233%华东师范大学河口海岸学国家重点实验室,上海,200062%东华大学环境科学与工程学院,上海,201620
2017
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1002-6819 |
| DOI | 10.11975/j.issn.1002-6819.2017.03.020 |
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| Summary: | 研究脱硫石膏(flue-gas desulfurization gypsum,FGDG)对土壤磷流失的阻控效果,既有利于开拓FGDG资源化利用新途径,又有助于丰富农业面源磷流失控制工程技术。借助土柱淋溶试验和人工边坡降雨侵蚀模拟试验,针对上海某火电厂的FGDG,系统研究不同质量配比(0、1%、2.5%和5%)的FGDG对农田土壤的固磷效果及机理。结果表明:1)FGDG的Ca2+将溶解态P转化成难溶态P,并将土壤无机磷中的Ca2-P、Al-P转化成Ca8-P和Ca10-P,有效控制溶解态磷(total dissolved phosphorus,TDP)直接流失,与对照组相比,施加FGDG对淋洗土柱TDP流失的阻控率达到92.8%-94.8%,而添加FGDG的各处理间无显著差异(P〉0.05);2)添加FGDG后,土壤的渗透性能和抗侵蚀能力极显著提高(P〈0.05),1%-5%的FGDG可使土柱渗透性能提升近10倍,添加FGDG的各处理组间无显著差异(P〉0.05),1%FGDG对坡面径流量的最大削减率为37.5%,对土壤侵蚀(泥沙流失)的最大削减率为59.5%,有利于控制泥沙结合态磷的流失;3)各FGDG处理对土柱中总磷(total phosphorus,TP)流失的阻控率为23.6%-79.5%,且随着配比增加而上升,与对照组相比,1%FGDG对人工边坡土壤TP流失的阻控率为61.5%。土壤流失的TDP量占流失TP的比例只有0.6%-6.1%,反映出改善土壤渗透性能、削减地表径流冲刷是FGDG控制P流失的主要机制,而Ca与P之间的沉淀反应属于从属机制。 |
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| Bibliography: | 11-2047/S Increased phosphorus (P) losses from land to waterbody via runoff and drainage are one of the important factorscausing eutrophication of surface waterbody. Flue gas desulfurization gypsum (FGDG) is a synthetic by-product generatedfrom the flue gas desulfurization process in coal power plants. Due to the high Ca2+ content of FGDG it can potentially be usedto immobilize P in soils. To study the effects of FGDG on soil P losses, not only to open up a new way of FGDG resourceutilization, but also to enrich engineering technologies for controlling agricultural non-point source P load. In this study, soilcolumn leaching experiment and artificial soil slope & rainfall simulation experiment were conducted to examine the impact ofFGDG which came from one of Shanghai coal-fired power plant, on the leaching and nmoff P losses from coastal plains soil ofChongming East Headland, Shanghai. Four mass rates of FGDG (0, 1%, 2.5% and 5%) were applied to soil column and twomass rates of FGDG (0 and I%) applied to artif |
| ISSN: | 1002-6819 |
| DOI: | 10.11975/j.issn.1002-6819.2017.03.020 |