阴/阳离子交换色谱-电感耦合等离子体质谱法分析鱼和贝类海产品砷的形态
采用阴（Hamilton PRP-X100柱）阳（Dionex Ionpac CS-10柱）离子交换色谱-电感耦合等离子体质谱联用技术,分别以pH 10.3的20mmol/L NH4HCO3和pH 2.0的5mmol/L吡啶溶液为流动相,建立了三价砷As（Ⅲ）、五价砷As（Ⅴ）、一甲基砷酸MMA、二甲基砷酸DMA、砷甜菜碱AsB、砷糖PO4、砷糖OH、砷糖SO3、砷糖SO4砷形态的分析方法。采用微波消解法和超声溶剂提取法对我国不同海域9种鱼和贝类海产品进行前处理,对砷含量及其化学形态进行分析。实验表明,鱼和贝海产品主要砷形态为砷甜菜碱AsB,其含量占可提取砷的42.8%～99.4%,大多数贝类...
Saved in:
| Published in | 分析化学 Vol. 39; no. 10; pp. 1577 - 1581 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | Chinese |
| Published |
江苏技术师范学院化学化T学院,常州,213001
2011
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 0253-3820 |
| DOI | 10.3724/SP.J.1096.2011.00000 |
Cover
| Abstract | 采用阴（Hamilton PRP-X100柱）阳（Dionex Ionpac CS-10柱）离子交换色谱-电感耦合等离子体质谱联用技术,分别以pH 10.3的20mmol/L NH4HCO3和pH 2.0的5mmol/L吡啶溶液为流动相,建立了三价砷As（Ⅲ）、五价砷As（Ⅴ）、一甲基砷酸MMA、二甲基砷酸DMA、砷甜菜碱AsB、砷糖PO4、砷糖OH、砷糖SO3、砷糖SO4砷形态的分析方法。采用微波消解法和超声溶剂提取法对我国不同海域9种鱼和贝类海产品进行前处理,对砷含量及其化学形态进行分析。实验表明,鱼和贝海产品主要砷形态为砷甜菜碱AsB,其含量占可提取砷的42.8%～99.4%,大多数贝类样品含有砷糖PO4、砷糖OH,其含量分别占可提取砷的32.5%～57.1%和1.4%～3.3%,少数样品含有DMA,其含量分别占可提取砷的5.7%～25.0%,所有样品无机砷的浓度均低于可提取砷的2.0%。在鱼和贝类海产品中,含砷化合物主要是毒性较低的有机砷,不会对人的健康带来危害。 |
|---|---|
| AbstractList | 采用阴（Hamilton PRP-X100柱）阳（Dionex Ionpac CS-10柱）离子交换色谱-电感耦合等离子体质谱联用技术,分别以pH 10.3的20mmol/L NH4HCO3和pH 2.0的5mmol/L吡啶溶液为流动相,建立了三价砷As（Ⅲ）、五价砷As（Ⅴ）、一甲基砷酸MMA、二甲基砷酸DMA、砷甜菜碱AsB、砷糖PO4、砷糖OH、砷糖SO3、砷糖SO4砷形态的分析方法。采用微波消解法和超声溶剂提取法对我国不同海域9种鱼和贝类海产品进行前处理,对砷含量及其化学形态进行分析。实验表明,鱼和贝海产品主要砷形态为砷甜菜碱AsB,其含量占可提取砷的42.8%～99.4%,大多数贝类样品含有砷糖PO4、砷糖OH,其含量分别占可提取砷的32.5%～57.1%和1.4%～3.3%,少数样品含有DMA,其含量分别占可提取砷的5.7%～25.0%,所有样品无机砷的浓度均低于可提取砷的2.0%。在鱼和贝类海产品中,含砷化合物主要是毒性较低的有机砷,不会对人的健康带来危害。 TS254.7; 采用阴(Hamilton PRP X100柱)阳(Dionex Ionpac CS- 10柱)离子交换色谱-电感耦合等离子体质谱联用技术,分别以pH 10.3的20 mmol/L NH4HCO3和pH 2.0的5 mmol/L吡啶溶液为流动相,建立了三价砷As(Ⅲ)、五价砷As(V)、一甲基砷酸MMA、二甲基砷酸DMA、砷甜菜碱AsB、砷糖PO4、砷糖OH、砷糖SO3、砷糖SO4砷形态的分析方法.采用微波消解法和超声溶剂提取法对我国不同海域9种鱼和贝类海产品进行前处理,对砷含量及其化学形态进行分析.实验表明,鱼和贝海产品主要砷形态为砷甜菜碱AsB,其含量占可提取砷的42.8％～99.4％,大多数贝类样品含有砷糖PO4、砷糖OH,其含量分别占可提取砷的32.5％～57.1％和1.4％～3.3％,少数样品含有DMA.其含量分别占可提取砷的5.7％～25.0％,所有样品无机砷的浓度均低于可提取砷的2.0％.在鱼和贝类海产品中,含砷化合物主要是毒性较低的有机砷,不会对人的健康带来危害. |
| Author | 李卫华 刘玉海 |
| AuthorAffiliation | 江苏技术师范学院化学化工学院,常州213001 |
| AuthorAffiliation_xml | – name: 江苏技术师范学院化学化T学院,常州,213001 |
| Author_FL | LI Wei-Hua LIU Yu-Hai |
| Author_FL_xml | – sequence: 1 fullname: LI Wei-Hua – sequence: 2 fullname: LIU Yu-Hai |
| Author_xml | – sequence: 1 fullname: 李卫华 刘玉海 |
| BookMark | eNotkEtLAlEYhs_CIDP_QZsWLWc8c86Zy1mGdEUoyL2cOTOjRo2lRLZTEFEokCyQoAsS1kbIVATNf-Nc_BeN6Ld5P3gevg_eDRCyc7YJwJYERawiEjs7FY9FCVJFRFCSRLiYEAhDJGMBawiug2ihkNVhACHRZC0M9HlrEJu3-l5n4nQbs_Gn-9D267_-T0_wnoZu5d0vdZxGzevWV8a06Q--A-z2n51a1X1rzHt_zuO9P3j1ehN3OJqNv5xm2fsYeS8VZ9p2S-VNsGaxi4IZXWUEJPf3kvFDIXFycBTfTQhcVrCgUmSqFDNDswgzoaQZhqlaMkKcKIuFYwtRmUJmUsyRLqlcU3TGkMaJxRWD4gjYWZ69ZbbF7HTqPHeTt4OHKauYKS76kCBEOPC2lx7P5Oz0dTYwr_LZS5a_S2FKVEIJxf-rbYaD |
| ClassificationCodes | TS254.7 |
| ContentType | Journal Article |
| Copyright | Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| Copyright_xml | – notice: Copyright © Wanfang Data Co. Ltd. All Rights Reserved. |
| DBID | 2RA 92L CQIGP ~WA 2B. 4A8 92I 93N PSX TCJ |
| DOI | 10.3724/SP.J.1096.2011.00000 |
| DatabaseName | 维普期刊资源整合服务平台 中文科技期刊数据库-CALIS站点 维普中文期刊数据库 中文科技期刊数据库- 镜像站点 Wanfang Data Journals - Hong Kong WANFANG Data Centre Wanfang Data Journals 万方数据期刊 - 香港版 China Online Journals (COJ) China Online Journals (COJ) |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| DocumentTitleAlternate | Analysis of Arsenic Speciation in Sea Fish and Shellfish by Using Anion/Cation Exchange High Performance Chromatography Coupled with Inductively Coupled Plasma-Mass Spectrometry |
| DocumentTitle_FL | Analysis of Arsenic Speciation in Sea Fish and Shellfish by Using Anion/Cation Exchange High Performance Chromatography Coupled with Inductively Coupled Plasma-Mass Spectrometry |
| EndPage | 1581 |
| ExternalDocumentID | fxhx201110023 39474949 |
| GroupedDBID | --K --M .~1 0R~ 1B1 1~. 1~5 29B 2B. 2C. 2RA 4.4 457 4G. 5GY 5VS 7-5 71M 8P~ 92E 92I 92L AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AARLI AAXUO ABFNM ABMAC ABXDB ABYKQ ACDAQ ACGFS ACNNM ACRLP ADBBV ADECG ADEZE ADMUD AEBSH AEKER AENEX AFKWA AFTJW AFZHZ AGHFR AGUBO AGYEJ AIEXJ AIKHN AITUG AJBFU AJOXV AJSZI ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BKOJK BLXMC CQIGP CS3 CW9 DU5 EBS EFJIC EFLBG EJD EO9 EP2 EP3 FDB FEDTE FIRID FLBIZ FNPLU FYGXN GBLVA HVGLF HZ~ J1W KOM M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 ROL SDF SDG SES SPC SPCBC SSK SSZ T5K TCJ TGP U1G U5L ~G- ~WA -02 -0B -SB -S~ .5D 188 4A8 5VR 5XA 5XC 8RM 92M 93N 9D9 9DB AAITT AATTM AAXKI AAYWO ABJNI ABWVN ACRPL ADNMO ADVLN AEIPS AFJKZ AFUIB AFXIZ AGCQF AGRNS AIIUN AKRWK ANKPU APXCP BBR BNPGV CAJEB CCEZO CDRFL CDYEO CJPJV CW7 FA0 J.9 JUIAU M~T PB1 PB6 PSX Q-- R-B RT2 S.. SSH T8R U1F U5B UY8 UZ4 W94 ~LN |
| ID | FETCH-LOGICAL-c563-792e793ad8f4ae018dde7f522c46e7f5c3f29590ae93c2b17c86baa28c4fc6d93 |
| ISSN | 0253-3820 |
| IngestDate | Thu May 29 04:00:21 EDT 2025 Wed Feb 14 09:54:56 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 10 |
| Keywords | 鱼和贝类海产品 高效液相色谱-电感耦合等离子体质谱 砷 形态分析 |
| Language | Chinese |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c563-792e793ad8f4ae018dde7f522c46e7f5c3f29590ae93c2b17c86baa28c4fc6d93 |
| Notes | The separation of arsenic compounds,including As,As,monomethylarsonate（MMA）,dimethylarsonate（DMA）,arsenobetaine（AsB）,arsenosugar PO4,arsenosugar OH,arsenosugar SO3 and arsenosugar SO4 were carried out in Hamilton PRP-X100 anion-exchange column with a mobile phase of 20 mmol/L NH4HCO3（pH 10.3） and on a Dionex Ionpac CS-10 cation-exchange column with a mobile phase of 5 mmol/L pyridinium（pH 2.0） for their analysis by ICP-MS.Total content of As and its different species of eight types of fish and shellfish in microwave-assisted digestion and ultrasonic solvent extraction were examined.The results showed that main components in all of the extracted fish and shellfish samples were arsenobetain（42.8%-99.4%）,while arsenosugar PO4 and arsenosugar OH were detected in most extracted shellfish samples（32.5%-57.1%,1.4%-3.3%）,DMA was detected in a few extracted samples（5.7%-25.0%）.In contrast,no inorganic arsenic in fish and shellfish samples occurred at levels below 2.0%. High preferment liquid chromatography-mass spect |
| PageCount | 5 |
| ParticipantIDs | wanfang_journals_fxhx201110023 chongqing_primary_39474949 |
| PublicationCentury | 2000 |
| PublicationDate | 2011 |
| PublicationDateYYYYMMDD | 2011-01-01 |
| PublicationDate_xml | – year: 2011 text: 2011 |
| PublicationDecade | 2010 |
| PublicationTitle | 分析化学 |
| PublicationTitleAlternate | Chinese Journal of Analytical Chemistry |
| PublicationTitle_FL | Chinese Journal of Analytical Chemistry |
| PublicationYear | 2011 |
| Publisher | 江苏技术师范学院化学化T学院,常州,213001 |
| Publisher_xml | – name: 江苏技术师范学院化学化T学院,常州,213001 |
| SSID | ssib001104858 ssib048394981 ssj0037577 ssib002258198 ssib007686865 ssib051370160 |
| Score | 1.8986468 |
| Snippet | 采用阴（Hamilton PRP-X100柱）阳（Dionex Ionpac CS-10柱）离子交换色谱-电感耦合等离子体质谱联用技术,分别以pH 10.3的20mmol/L NH4HCO3和pH... TS254.7; 采用阴(Hamilton PRP X100柱)阳(Dionex Ionpac CS- 10柱)离子交换色谱-电感耦合等离子体质谱联用技术,分别以pH 10.3的20 mmol/L NH4HCO3和pH 2.0的5... |
| SourceID | wanfang chongqing |
| SourceType | Aggregation Database Publisher |
| StartPage | 1577 |
| SubjectTerms | 形态分析 砷 高效液相色谱-电感耦合等离子体质谱 鱼和贝类海产品 |
| Title | 阴/阳离子交换色谱-电感耦合等离子体质谱法分析鱼和贝类海产品砷的形态 |
| URI | http://lib.cqvip.com/qk/93919X/201110/39474949.html https://d.wanfangdata.com.cn/periodical/fxhx201110023 |
| Volume | 39 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3NS9xAFA9qD-2l9JNqW_HQOUaTyWQyc0x2s4iHUugWvC1JNtHT2o8VxENRkKLQgtQWpNAPpNhepLUqgtb_xv3wv-h7k2x2Kwv9WEKYnXnz5vfeS_LeJPOhafdYmEQJ-E3dEZGts0QGurBDoUPPwaBRLGIzHSB7n08-YlPT9vTA4LeeUUvz9XA8Wuw7r-R_rAp5YFecJfsPls2ZQgakwb5wBgvD-a9sTHxJpCAeAxadtEV8h7iceB7xbeIWiTSIz4jnEpcRnxNRJC4lviBCEk8lPIN4po7VJNDZiogRWVJEBvICRsBFCMW6iDX7twEJS3FkxBU5a2QIsKSNxMBEcMyRvqolkcArqCYoEYWsuixiE1jkqeo28ZyOGI4itiAGVjAMVQTgXYQNRV4qIUfw6UYtnei7HwAbG5U8E8TNX1QqEpDVVyRQ4mUJ4XdJFDup9AKEqJcMa-_LFLP7GkWVmx3dekSUFE4XoWJ7BeKWlAhCaVsgNmHl2JSNpZLuPOw8p9yHmhYypnD4SpUSB8FS_Mho9rgCalu6JajR67fSRaA696fR44VMO9saJ87-pso-7y0th-L1-fDB-BSuKsazBW3x140O8jGbycLsAhLgmr3WoHaBOpzjliHjz7sOAvquXHQ_mzOIvpkU-Zgry7HVVqi5OOlcVsQx0Q8FrncyO1ebeQJRnJpUV0uC2kxP_Fe-ol3OOm5jbnoXXtUGFmevaRcLnf0Sr2vh2eb-xNnmXmv7uLGzfnr0uflqq732o_19V2-9OWiufGwvbTfWV1s7axnFyUZ7_ysUN_feNlZfND-sn-3-bLx-2d5_39o9bh4cnh59aWwstz4dtt6tNE62mkvLN7RyyS8XJvVsBxM9srmlO5LG4P-CqkhYEBumgFjCSaDHEzGOichKqLSlEcTSimhoOpHgYRBQEbEk4lVp3dSGanO1-JY2xm0W0qoZyyoPGAQwwmTAgUmDBjxm0hnWRnJVVR6nC9VUQPsOrj41rI1muqtkT69nld_MOfIngtvapfRjCh53tKH60_n4LkTj9XBUXQG_ACWntTk |
| linkProvider | Elsevier |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%E9%98%B4%2F%E9%98%B3%E7%A6%BB%E5%AD%90%E4%BA%A4%E6%8D%A2%E8%89%B2%E8%B0%B1-%E7%94%B5%E6%84%9F%E8%80%A6%E5%90%88%E7%AD%89%E7%A6%BB%E5%AD%90%E4%BD%93%E8%B4%A8%E8%B0%B1%E6%B3%95%E5%88%86%E6%9E%90%E9%B1%BC%E5%92%8C%E8%B4%9D%E7%B1%BB%E6%B5%B7%E4%BA%A7%E5%93%81%E7%A0%B7%E7%9A%84%E5%BD%A2%E6%80%81&rft.jtitle=%E5%88%86%E6%9E%90%E5%8C%96%E5%AD%A6&rft.au=%E6%9D%8E%E5%8D%AB%E5%8D%8E&rft.au=%E5%88%98%E7%8E%89%E6%B5%B7&rft.date=2011&rft.pub=%E6%B1%9F%E8%8B%8F%E6%8A%80%E6%9C%AF%E5%B8%88%E8%8C%83%E5%AD%A6%E9%99%A2%E5%8C%96%E5%AD%A6%E5%8C%96T%E5%AD%A6%E9%99%A2%2C%E5%B8%B8%E5%B7%9E%2C213001&rft.issn=0253-3820&rft.volume=39&rft.issue=10&rft.spage=1577&rft.epage=1581&rft_id=info:doi/10.3724%2FSP.J.1096.2011.00000&rft.externalDocID=fxhx201110023 |
| thumbnail_s | http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fimage.cqvip.com%2Fvip1000%2Fqk%2F93919X%2F93919X.jpg http://utb.summon.serialssolutions.com/2.0.0/image/custom?url=http%3A%2F%2Fwww.wanfangdata.com.cn%2Fimages%2FPeriodicalImages%2Ffxhx%2Ffxhx.jpg |