Experimental and simulation study of inert gas mixture inhibiting coal spontaneous combustion

• Published in: Scientific reports Vol. 14; no. 1; pp. 4305 - 12
• Main Authors: Wang, Xinning, Wang, Lei, Li, Weidong, Liu, Dongyang
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 21.02.2024; Nature Publishing Group; Nature Portfolio
• Subjects: 639/166; 639/638; 704/172; Carbon dioxide; Coal; Coal mines; Combustion; Free radical reaction; Free radicals; Gases; Heat transfer; High-temperature environment; Humanities and Social Sciences; Inert mixed gas; Inhibit spontaneous combustion; Low temperature; multidisciplinary; Oxidation; Science; Science (multidisciplinary); Spontaneous combustion of coal; Inert mixed gas; Free radical reaction; High-temperature environment; Inhibit spontaneous combustion; Spontaneous combustion of coal
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-024-53979-0

To explore the mechanism of inhibiting spontaneous combustion of coal by mixed gases, the low-temperature oxidation characteristics of coal under different components of mixed gases were analyzed. ESR and FTIR experiments were used to investigate the effects of different gas mixtures on the activity of coal during low-temperature oxidation and the oxidation reaction of coal surface functional groups. The mechanism of chemical oxygen inhibition of mixed gas was studied by density functional theory. The results show that the larger the CO 2 component in the mixed gas, the higher the ability to inhibit coal oxidation. The concentration of free radicals in coal under dry air condition is higher than that under inert mixed gas condition during oxidation heating at 30–230 °C. The oxidation ability of –CH 3 , –OH and oxygen-containing functional groups in the mixed gas reaction is inhibited. Through quantum chemistry calculation, it is found that the mixed gas increases the activation energy of free radicals and reduces the heat release of the reaction. This study provides theoretical reference for coal mine thermal disaster.