The chemistry of multi-component and hierarchical framework compounds
Multi-component hierarchically porous materials are an emerging class of materials with tailored compositions, tunable distribution and sophisticated applications. An increasing demand for multifunctionalities and hierarchical structures has resulted in extensive studies on multi-component hierarchi...
Saved in:
| Published in | Chemical Society reviews Vol. 48; no. 18; pp. 4823 - 4853 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
16.09.2019
Royal Society of Chemistry (RSC) |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0306-0012 1460-4744 1460-4744 |
| DOI | 10.1039/c9cs00250b |
Cover
| Summary: | Multi-component hierarchically porous materials are an emerging class of materials with tailored compositions, tunable distribution and sophisticated applications. An increasing demand for multifunctionalities and hierarchical structures has resulted in extensive studies on multi-component hierarchical metal-organic frameworks and other open framework compounds. This review article focuses on recent advances in multi-component and hierarchical framework materials, covering the design and synthetic strategies of these architectures, their characterization, and the latest applications. Multivariate MOFs prepared under various synthetic conditions (one-pot or post-synthetic) and their building block distributions are introduced and summarized. This is followed by a short review of characterization techniques including solid-state NMR and photothermal induced resonance, and their potential applications in gas storage, separation, heterogeneous catalysis, guest delivery, and luminescence. Furthermore, guided by the same design principles, the synthesis and applications of multi-component hierarchical covalent-organic frameworks, metal-organic cages and porous organic cages are introduced and discussed. Together, this review is expected to provide a library of multi-component hierarchically porous compounds, which could also guide the state-of-the-art design and discovery of future porous materials with unprecedented tunability, synergism and precision.
This review is expected to provide a library of multi-component hierarchically porous compounds, which shall guide the state-of-the-art design of future porous materials with unprecedented tunability, synergism and precision. |
|---|---|
| Bibliography: | Kunyu Wang received his BSc in Chemistry (Po-Ling class) from Nankai University in 2018, where he studied the synthesis and simulation of metal-organic frameworks under the guidance of Prof. Wei Shi. In 2017, he went to Northwestern University as an undergraduate researcher in Dr T. David Harris' group to develop semiquinoid molecular magnets. In 2018, Kunyu started graduate school at Texas A&M University and joined Prof. Hong-Cai Zhou's research group. His research interest now focuses on developing novel strategies to design multivariate and hierarchically porous metal-organic frameworks. Liang Feng received his BSc in Chemistry from Wuhan University in 2016, where he worked on the synthesis of porous materials for gas separation under the guidance of Prof. Hexiang Deng. In 2016, after an undergraduate research stay in Prof. Mohamed Eddaoudi's group at King Abdullah University of Science and Technology, he joined Prof. Hong-Cai Zhou's group at Texas A&M University. He is now a PhD candidate at Department of Chemistry, TAMU. His research interests focus on the development of synthetic strategies for multicomponent porous materials for efficient catalysis, and the hierarchical assembly of mesoscopic structures for sophisticated applications. Gregory Day received his BA and MS in Chemistry at Brandeis University in 2010 under the supervision of Professor Christine Thomas. After a stint in the chemical industry he joined the graduate program at the Texas A&M University Department of Chemistry in 2015. Gregory's current research in the laboratory of Professor Hong-Cai Joe Zhou focuses on the formation processes and applications of amorphous porous materials. Hong-Cai Zhou obtained his PhD in 2000 from Texas A&M University under the supervision of F. A. Cotton. After a postdoctoral stint at Harvard University with R. H. Holm, he joined the faculty of Miami University, Oxford, in 2002. He moved to Texas A&M University in 2008, was promoted to a Davidson Professor of Science in 2014, and was appointed the Robert A. Welch Chair in Chemistry in 2015. Since 2014, he has been listed as a Highly Cited Researcher by Thomson Reuters every year, and in 2016 he was elected as a fellow of the AAAS, ACS, and RSC. In 2017 he was given the Distinguished Achievement award in research by TAMU's Association of Former Students. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 ObjectType-Review-3 content type line 23 USDOE Office of Science (SC), Basic Energy Sciences (BES) SC0001015; FE0026472 USDOE Office of Fossil Energy and Carbon Management (FECM) |
| ISSN: | 0306-0012 1460-4744 1460-4744 |
| DOI: | 10.1039/c9cs00250b |