Enhancement of tensile, electrical and thermal properties of epoxy nanocomposites through chemical hybridization of polypyrrole and graphene oxide

• Published in: Polymer testing Vol. 60; pp. 173 - 186
• Main Authors: Moosaei, Roya, Sharif, Mehdi, Ramezannezhad, Amir
• Format: Journal Article
• Language: English
• Published: Barking Elsevier Ltd 01.07.2017; Elsevier BV
• Subjects: Chemical synthesis; Diffraction; Electrical resistivity; Fillers; Fourier transforms; Graphene; Load transfer; Mechanical properties; Microstructure; Modulus of elasticity; Nanocomposite; Nanocomposites; Particle physics; Polymerization; PPy-GO hybrids; Scanning electron microscopy; Synergistic effect; Tensile properties; Thermal analysis; Thermodynamic properties; Transmission electron microscopy; X-ray diffraction; Mechanical properties; PPy-GO hybrids; Nanocomposite; Synergistic effect
• ISSN: 0142-9418; 1873-2348
• DOI: 10.1016/j.polymertesting.2017.03.022

This paper presents the properties of epoxy nanocomposites, prepared using a synthesized hybrid Polypyrrole-Graphene Oxide (PPy-GO) filler, via in-situ chemical polymerization, at various filler loadings (i.e., 0.5–2 w. t %). The microstructures and properties of the PPy-GO hybrids and epoxy nanocomposites were studied via Fourier transform infrared (FTIR), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), mechanical (Tensile Properties), electrical, Dynamic mechanical thermal analysis (DMTA) and thermogravimetric analyses (TGA). Morphological study demonstrated that varying the nanofiller nature (PPy-GOs, PPy or GO) lead to different states of dispersion. Mechanical, electrical and thermal analysis demonstrated that the hybrid concentration and its architecture (PPy:GO ratio) are interesting factors significantly affected the properties of the epoxy based nanocomposites. On the other hand, the mechanical performance of the cured nanocomposites outperformed the PPy-GO, with enhancements of 78% and 51% of Young's modulus and strength, respectively. Here it has been established that the embedding of PPy-GO hybrids into pristine epoxy endows optimum dispersion of PPy and GO as well as better interfacial adhesion between the fillers and matrix, which results in a significant improvement in load transfer effectiveness. Electrical conductivity measurements showed that conductivity of epoxy filled nanocomposites increased up 10−4 S/cm for Epoxy/PPy-GO nanocomposites. DMTA test indicated that incorporation of PPy-GO resulted in a significantly increase in Tg of the resultant nanocomposites, which is attributed to the highly exfoliation structure and the stronger interfacial interaction. The PPy-GO particles enhanced electrical, thermal and mechanical properties of nanocomposites, confirming the synergistic effect of PPy-GO as multifunctional filler.