Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

The direct functionalization of heterocyclic compounds has emerged as one of the most important topics in the field of metal-catalyzed C-H bond activation due to the fact that products are an important synthetic motif in organic synthesis, the pharmaceutical industry, and materials science. This cri...

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Bibliographic Details
Published in	Chemical Society reviews Vol. 40; no. 10; pp. 5068 - 5083
Main Authors	Cho, Seung Hwan, Kim, Ji Young, Kwak, Jaesung, Chang, Sukbok
Format	Journal Article
Language	English
Published	England 01.01.2011
Subjects	Activation amination arylation Bonding Carbon - chemistry Carbon-carbon composites carbon-hydrogen bond activation Catalysis catalysts catalytic activity chemical bonding dehydrogenation Heterocyclic compounds Hydrogen - chemistry Joining materials science Nitrogen - chemistry Oxidation-Reduction pharmaceutical industry regioselectivity Strategy Synthesis Transition Elements - chemistry Transition metals
Online Access	Get full text
ISSN	0306-0012 1460-4744 1460-4744
DOI	10.1039/c1cs15082k

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Abstract	The direct functionalization of heterocyclic compounds has emerged as one of the most important topics in the field of metal-catalyzed C-H bond activation due to the fact that products are an important synthetic motif in organic synthesis, the pharmaceutical industry, and materials science. This critical review covers the recent progresses on the regioselective dehydrogenative direct coupling reaction of heteroarenes, including arylation, olefination, alkynylation, and amination/amidation mainly utilizing transition metal catalysts (113 references).
AbstractList	The direct functionalization of heterocyclic compounds has emerged as one of the most important topics in the field of metal-catalyzed C-H bond activation due to the fact that products are an important synthetic motif in organic synthesis, the pharmaceutical industry, and materials science. This critical review covers the recent progresses on the regioselective dehydrogenative direct coupling reaction of heteroarenes, including arylation, olefination, alkynylation, and amination/amidation mainly utilizing transition metal catalysts (113 references). The direct functionalization of heterocyclic compounds has emerged as one of the most important topics in the field of metal-catalyzed C-H bond activation due to the fact that products are an important synthetic motif in organic synthesis, the pharmaceutical industry, and materials science. This critical review covers the recent progresses on the regioselective dehydrogenative direct coupling reaction of heteroarenes, including arylation, olefination, alkynylation, and amination/amidation mainly utilizing transition metal catalysts (113 references).The direct functionalization of heterocyclic compounds has emerged as one of the most important topics in the field of metal-catalyzed C-H bond activation due to the fact that products are an important synthetic motif in organic synthesis, the pharmaceutical industry, and materials science. This critical review covers the recent progresses on the regioselective dehydrogenative direct coupling reaction of heteroarenes, including arylation, olefination, alkynylation, and amination/amidation mainly utilizing transition metal catalysts (113 references).
Author	Cho, Seung Hwan Chang, Sukbok Kim, Ji Young Kwak, Jaesung
Author_xml	– sequence: 1 givenname: Seung Hwan surname: Cho fullname: Cho, Seung Hwan – sequence: 2 givenname: Ji Young surname: Kim fullname: Kim, Ji Young – sequence: 3 givenname: Jaesung surname: Kwak fullname: Kwak, Jaesung – sequence: 4 givenname: Sukbok surname: Chang fullname: Chang, Sukbok
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/21643614$$D View this record in MEDLINE/PubMed
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Snippet	The direct functionalization of heterocyclic compounds has emerged as one of the most important topics in the field of metal-catalyzed C-H bond activation due... The direct functionalization of heterocyclic compounds has emerged as one of the most important topics in the field of metal-catalyzed C–H bond activation due...
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SubjectTerms	Activation amination arylation Bonding Carbon - chemistry Carbon-carbon composites carbon-hydrogen bond activation Catalysis catalysts catalytic activity chemical bonding dehydrogenation Heterocyclic compounds Hydrogen - chemistry Joining materials science Nitrogen - chemistry Oxidation-Reduction pharmaceutical industry regioselectivity Strategy Synthesis Transition Elements - chemistry Transition metals
Title	Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation
URI	https://www.ncbi.nlm.nih.gov/pubmed/21643614 https://www.proquest.com/docview/1019623123 https://www.proquest.com/docview/2352432675 https://www.proquest.com/docview/893276913
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