Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

The direct functionalization of heterocyclic compounds has emerged as one of the most important topics in the field of metal-catalyzed C-H bond activation due to the fact that products are an important synthetic motif in organic synthesis, the pharmaceutical industry, and materials science. This cri...

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Published inChemical Society reviews Vol. 40; no. 10; pp. 5068 - 5083
Main Authors Cho, Seung Hwan, Kim, Ji Young, Kwak, Jaesung, Chang, Sukbok
Format Journal Article
LanguageEnglish
Published England 01.01.2011
Subjects
Activation
amination
arylation
Bonding
Carbon - chemistry
Carbon-carbon composites
carbon-hydrogen bond activation
Catalysis
catalysts
catalytic activity
chemical bonding
dehydrogenation
Heterocyclic compounds
Hydrogen - chemistry
Joining
materials science
Nitrogen - chemistry
Oxidation-Reduction
pharmaceutical industry
regioselectivity
Strategy
Synthesis
Transition Elements - chemistry
Transition metals
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ISSN0306-0012
1460-4744
1460-4744
DOI10.1039/c1cs15082k

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Summary:The direct functionalization of heterocyclic compounds has emerged as one of the most important topics in the field of metal-catalyzed C-H bond activation due to the fact that products are an important synthetic motif in organic synthesis, the pharmaceutical industry, and materials science. This critical review covers the recent progresses on the regioselective dehydrogenative direct coupling reaction of heteroarenes, including arylation, olefination, alkynylation, and amination/amidation mainly utilizing transition metal catalysts (113 references).
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ISSN:0306-0012
1460-4744
1460-4744
DOI:10.1039/c1cs15082k