Sorption isotherms, thermodynamic properties and glass transition temperature of mucilage extracted from chia seeds (Salvia hispanica L.)

• Published in: Carbohydrate polymers Vol. 121; pp. 411 - 419
• Main Authors: Velázquez-Gutiérrez, Sandra Karina, Figueira, Ana Cristina, Rodríguez-Huezo, María Eva, Román-Guerrero, Angélica, Carrillo-Navas, Hector, Pérez-Alonso, César
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 05.05.2015
• Subjects: enthalpy; Enthalpy–entropy compensation; entropy; equations; freeze drying; Glass transition temperature; Minimum integral entropy; Mucilage; Plant Mucilage - chemistry; Salvia - chemistry; Salvia hispanica; seeds; Seeds - chemistry; Sorption isotherms; Thermodynamic properties; Transition Temperature; Vitrification; water activity; Enthalpy–entropy compensation; Minimum integral entropy; Mucilage; Thermodynamic properties; Glass transition temperature; Sorption isotherms
• ISSN: 0144-8617; 1879-1344; 1879-1344
• DOI: 10.1016/j.carbpol.2014.11.068

•The sorption isotherms of freeze-dried chia mucilage presented a sigmoidal shape.•The GAB equation was useful for modelling moisture sorption of the mucilage.•The pore radius of the mucilage varied from 0.87 to 6.44nm.•The minimum integral entropy was in the range of 0.34–0.53 of aW.•The Tg of the mucilage was found between 42.93 and 57.93°C. Freeze-dried chia mucilage adsorption isotherms were determined at 25, 35 and 40°C and fitted with the Guggenheim–Anderson–de Boer model. The integral thermodynamic properties (enthalpy and entropy) were estimated with the Clausius–Clapeyron equation. Pore radius of the mucilage, calculated with the Kelvin equation, varied from 0.87 to 6.44nm in the temperature range studied. The point of maximum stability (minimum integral entropy) ranged between 7.56 and 7.63kg H2O per 100kg of dry solids (d.s.) (water activity of 0.34–0.53). Enthalpy–entropy compensation for the mucilage showed two isokinetic temperatures: (i) one occurring at low moisture contents (0–7.56kg H2O per 100kg d.s.), controlled by changes in water entropy; and (ii) another happening in the moisture interval of 7.56–24kg H2O per 100kg d.s. and was enthalpy driven. The glass transition temperature Tg of the mucilage fluctuated between 42.93 and 57.93°C.