Application of neural network adaptive filter method to simultaneous detection of polymetallic ions based on ultraviolet-visible spectroscopy

• Published in: Frontiers in chemistry Vol. 12; p. 1409527
• Main Authors: Wu, Bo, Zhou, Fengbo
• Format: Journal Article
• Language: English
• Published: Switzerland Frontiers Media S.A 05.09.2024
• Subjects: Chemistry; neural network adaptive filter; noise reduction; quantitative analysis; signal processing; ultraviolet-visible spectroscopy; noise reduction; quantitative analysis; signal processing; ultraviolet-visible spectroscopy; neural network adaptive filter
• ISSN: 2296-2646; 2296-2646
• DOI: 10.3389/fchem.2024.1409527

A novel neural network adaptive filter algorithm is proposed to address the challenge of weak spectral signals and low accuracy in micro-spectrometer detection. This algorithm bases on error backpropagation (BP) and least mean square (LMS), introduces an innovative BP neural network model incorporating instantaneous error function and error factor to optimize the learning process. It establishes a network relationship through the input signal, output signal, error and step factor of the adaptive filter, and defines a training optimization learning method for this relationship. To validate the effectiveness of the algorithm, experiments were conducted on simulated noisy signals and actual spectral signals. Results show that the algorithm effectively denoises signals, reduces noise interference, and enhances signal quality, the SNR of the proposed algorithm is 3–4 dB higher than that of the traditional algorithm. The experimental spectral results showed that the proposed neural network adaptive filter algorithm combined with partial least squares regression is suitable for simultaneous detection of copper and cobalt based on ultraviolet-visible spectroscopy, and has broad application prospects.