Amorphous Carbon Coatings for Total Knee Replacements—Part II: Tribological Behavior

• Published in: Polymers Vol. 13; no. 11; p. 1880
• Main Authors: Rothammer, Benedict, Marian, Max, Neusser, Kevin, Bartz, Marcel, Böhm, Thomas, Krauß, Sebastian, Schroeder, Stefan, Uhler, Maximilian, Thiele, Simon, Merle, Benoit, Kretzer, Jan Philippe, Wartzack, Sandro
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 05.06.2021; MDPI
• Subjects: Arthritis; Biocompatibility; Carbon; Chemical vapor deposition; Chromium; Coatings; Continuous coating; Diamond films; Diamond-like carbon; Diamond-like carbon films; Femoral components; Friction; Hydrogenation; Intermetallic compounds; Investigations; Knee; Loosening; Lubricants & lubrication; Lubrication; Mechanical properties; Orthopaedic implants; Pin on disk tests; Polyethylene; Raman spectroscopy; Scanning microscopy; Service life; Spallation; Stainless steel; Titanium; Titanium base alloys; Transplants & implants; Tribology; Tungsten; Ultra high molecular weight polyethylene; Wear particles; total knee arthroplasty; biotribology; Ti64; UHMWPE; DLC coating; biomedical applications; wear; CoCr; friction; pin-on-disk
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym13111880

Diamond-like carbon coatings may decrease implant wear, therefore, they are helping to reduce aseptic loosening and increase service life of total knee arthroplasties (TKAs). This two-part study addresses the development of such coatings for ultrahigh molecular weight polyethylene (UHMWPE) tibial inlays as well as cobalt-chromium-molybdenum (CoCr) and titanium (Ti64) alloy femoral components. While the deposition of a pure (a-C:H) and tungsten-doped hydrogen-containing amorphous carbon coating (a-C:H:W) as well as the detailed characterization of mechanical and adhesion properties were the subject of Part I, the tribological behavior is studied in Part II. Pin-on-disk tests are performed under artificial synovial fluid lubrication. Numerical elastohydrodynamic lubrication modeling is used to show the representability of contact conditions for TKAs and to assess the influence of coatings on lubrication conditions. The wear behavior is characterized by means of light and laser scanning microscopy, Raman spectroscopy, scanning electron microscopy and particle analyses. Although the coating leads to an increase in friction due to the considerably higher roughness, especially the UHMWPE wear is significantly reduced up to a factor of 49% (CoCr) and 77% (Ti64). Thereby, the coating shows continuous wear and no sudden failure or spallation of larger wear particles. This demonstrated the great potential of amorphous carbon coatings for knee replacements.