White-Light Electroluminescence with Tetraphenylethylene as Emitting Layer of Aggregation-Induced Emissions Enhancement

Tetraphenylethylene (TPE) based molecules with easy synthesis, good thermal stability, and especially their aggregation-induced emissions enhancement (AIEE) effect recently become attractive organic emitting materials due to their potentially practical application in OLEDs. Herein, the AIEE behavior...

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Published inChinese journal of chemistry Vol. 30; no. 10; pp. 2488 - 2494
Main Author 罗建芳 王晓宏 王筱梅 苏文明 陶绪堂 陈志刚
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.10.2012
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
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ISSN1001-604X
1614-7065
DOI10.1002/cjoc.201200195

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Summary:Tetraphenylethylene (TPE) based molecules with easy synthesis, good thermal stability, and especially their aggregation-induced emissions enhancement (AIEE) effect recently become attractive organic emitting materials due to their potentially practical application in OLEDs. Herein, the AIEE behaviors of tetraphenylethylene dyes (TMTPE and TBTPE) were investigated. Fabricated luminesent device using TMTPE dye as emitting layer displays two strong emitting bands: the blue emission coming from the first-step aggregation and the yellow emission attrib- uted to the second-step aggregation. Thus, it can be utilized to fabricate the white-light OLEDs (WOLEDs) of the single-emitting-component. A three-layer device with the brightness of 1200 cd·m^-2 and current efficiency of 0.78 cd·A^-1 emits the close to white light with the CIE coordinates of x=0.333 and y=0.358, when applied voltage from 8-13 V, verifying that the TPE-based dyes of AIEE effect can be effectively applied in single-emitting- component WOLEDs fabrication.
Bibliography:Tetraphenylethylene (TPE) based molecules with easy synthesis, good thermal stability, and especially their aggregation-induced emissions enhancement (AIEE) effect recently become attractive organic emitting materials due to their potentially practical application in OLEDs. Herein, the AIEE behaviors of tetraphenylethylene dyes (TMTPE and TBTPE) were investigated. Fabricated luminesent device using TMTPE dye as emitting layer displays two strong emitting bands: the blue emission coming from the first-step aggregation and the yellow emission attrib- uted to the second-step aggregation. Thus, it can be utilized to fabricate the white-light OLEDs (WOLEDs) of the single-emitting-component. A three-layer device with the brightness of 1200 cd·m^-2 and current efficiency of 0.78 cd·A^-1 emits the close to white light with the CIE coordinates of x=0.333 and y=0.358, when applied voltage from 8-13 V, verifying that the TPE-based dyes of AIEE effect can be effectively applied in single-emitting- component WOLEDs fabrication.
31-1547/O6
white-light, OLED, aggregation, tetraphenylethylene
Luo, Jianfang Wang, Xiaohong Wang, Xiaomei Su, Wenming Tao, Xutang Chert, Zhigang Key Laboratory for Environmental Functional Materials of Jiangsu Province,Institute of Chemistry and Bioengineering, Suzhou University of Science and Technology, Suzhou, Jiangsu 215009, China t, State Key Laboratory of Crystal Materials, Shandong University, dinah, Shandong 250100, China ~' Printable Electronics Research Center, Suzhou Institute of Nanotech and Nanobionics, Jiangsu 215125, China
the Natural Science Foundation of Jiangsu Province Education Committee - No. 11KJA430003
Open Project of Jiangsu Key Laboratory for Advanced Optical Manufacture Technologies - No. KJS1102
ark:/67375/WNG-KSWPWHSS-F
ArticleID:CJOC201200195
the National Natural Science Foundation of China - No. 50973077
the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) for financial supports
istex:E183FBC66B89C1197D3143BD59DC714B88B45BA8
Project of Person with Ability of Jiangsu Province - No. 2010-xcl-015
ObjectType-Article-1
SourceType-Scholarly Journals-1
content type line 14
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201200195