Electrosynthesis of Chirality Conducting Poly[N-（9-fluorenylmethoxycarbonyl）-L-phenylalanine] with Good Blue Light-Emitting Properties

Poly[N-（9-fluorenylmethoxycarbonyl）-L-phenylalanine] （PN9FPA） films with good fluorescence properties and chirality were prepared electrochemically by direct anodic oxidation of N-（9-fluorenylmethoxycarbonyl）- L-phenylalanine （N9FPA） in boron trifluoride diethyletherate （BFEE）. Fourier transform inf...

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Published inChinese journal of chemistry Vol. 30; no. 3; pp. 507 - 511
Main Author 来存远 郭文娟 唐新德 裴梅山
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.03.2012
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
blue-light emitter
Boron
chirality
Fluorescence
Fourier transforms
good solubility
Infrared spectroscopy
L-苯丙氨酸
poly[N-(9-fluorenylmethoxycarbonyl)-L-phenylalanine]
Polymers
Spectrum analysis
傅里叶变换红外光谱
发光性质
导电
手性
芴
荧光性能
蓝色
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ISSN1001-604X
1614-7065
DOI10.1002/cjoc.201100087

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Summary:Poly[N-（9-fluorenylmethoxycarbonyl）-L-phenylalanine] （PN9FPA） films with good fluorescence properties and chirality were prepared electrochemically by direct anodic oxidation of N-（9-fluorenylmethoxycarbonyl）- L-phenylalanine （N9FPA） in boron trifluoride diethyletherate （BFEE）. Fourier transform infrared spectroscopy measurement showed that the polymerization of N9FPA occurred mainly at the C（2） and C（7） positions. The fluo- rescence spectra indicated that PN9FPA films were blue-light emitters. In addition, the structures and properties of the monomer and the polymers were characterized and evaluated with CV, UV, TGA and SEM.
Bibliography:31-1547/O6
Poly[N-（9-fluorenylmethoxycarbonyl）-L-phenylalanine] （PN9FPA） films with good fluorescence properties and chirality were prepared electrochemically by direct anodic oxidation of N-（9-fluorenylmethoxycarbonyl）- L-phenylalanine （N9FPA） in boron trifluoride diethyletherate （BFEE）. Fourier transform infrared spectroscopy measurement showed that the polymerization of N9FPA occurred mainly at the C（2） and C（7） positions. The fluo- rescence spectra indicated that PN9FPA films were blue-light emitters. In addition, the structures and properties of the monomer and the polymers were characterized and evaluated with CV, UV, TGA and SEM.
chirality, poly[N-（9-fluorenylmethoxycarbonyl）-L-phenylalanine], good solubility, blue-light emitter
Lai, Cunyuan Guo, Wenjuan Tang, Xinde Pei, Meishana a School of Chemistry and Chemical Engineering, University ofJinan, Jinan, Shandong 250022, China b Institute of New Materials＇, Shandong Jiaotong University, Jinan, Shandong 250023, China
the Natural Science Foundation of Shandong Province - No. Y2008B61
ArticleID:CJOC201100087
istex:D33E747B80EDBB1BAA02E6256ED30490C15F3F62
ark:/67375/WNG-S1X45CXQ-Z
the National Natural Science Foundation of China - No. 50872042
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201100087