Decontamination of chemical warfare agents using perchloroethylene–Marlowet IHF–H2O-based microemulsions: wetting and extraction properties on realistic surfaces

• Published in: Colloid and polymer science Vol. 286; no. 4; pp. 417 - 426
• Main Authors: Wellert, Stefan, Imhof, Henrik, Dolle, Michael, Altmann, Hans-Jürgen, Richardt, André, Hellweg, Thomas
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer-Verlag 01.04.2008; Springer; Springer Nature B.V
• Subjects: Biological & chemical weapons; Characterization and Evaluation of Materials; Chemical warfare; Chemistry; Chemistry and Materials Science; Colloidal state and disperse state; Complex Fluids and Microfluidics; Contaminants; Contamination; Decontamination; Emulsions. Microemulsions. Foams; Exact sciences and technology; Extraction; Food Science; General and physical chemistry; Microemulsions; Nanotechnology and Microengineering; Original Contribution; Physical Chemistry; Polymer Sciences; Sheet metal; Soft and Granular Matter; Wetting; Solubility parameter; Chemical warfare agent; Microemulsions; Contact angle; Decontamination; Wetting; Chlorocarbon; Solubility; Extraction; Microemulsion; Chemical warfare agent· Solubility parameter
• ISSN: 0303-402X; 1435-1536
• DOI: 10.1007/s00396-007-1788-4

At the present time, considerable efforts are being made to develop new media for the decontamination of a variety of toxic compounds. In the present contribution, new microemulsions with promising properties are presented. Moreover, the decontamination of surfaces, with an emphasis on varnished metal surfaces of exterior and interior equipment, is investigated using these microemulsions. Studies of the phase behavior of the system water–perchloroethylene–IHF–2-propanol are reported and the microemulsion phases are recognized. The wetting behavior on contaminated surfaces and the extraction capabilities with respect to contaminants are essential for an efficient decontamination. Hence, suitable microemulsions are identified on the basis of these properties. The decontamination efficiency of these microemulsions is first estimated on the basis of the ability to wet typical chemical nonresistant varnished steel sheets, which are authentic model systems for real surfaces. Afterwards, promising microemulsions and, as reference, different solvents are tested with respect to their capability to solubilize sulfur-mustard agent, again using realistic surfaces contaminated with this chemical warfare agent. Several microemulsions are found, which have the desired properties.