Effect of degree of deacetylation of chitosan on adsorption capacity and reusability of chitosan/polyvinyl alcohol/TiO2 nano composite

• Published in: International journal of biological macromolecules Vol. 104; no. Pt A; pp. 1133 - 1142
• Main Authors: Habiba, Umma, Joo, Tan Chin, Siddique, Tawsif A., Salleh, Areisman, Ang, Bee Chin, Afifi, Amalina M.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.11.2017
• Subjects: Adsorption; Chitosan; Degree of deacetylation; Fourier transform infrared spectroscopy; hydrolysis; Kinetic studies and reusability test; kinetics; methyl orange; nanocomposites; scanning electron microscopy; sorption isotherms; temperature; thermogravimetry; titanium dioxide; weight loss; X-ray diffraction; Degree of deacetylation; Chitosan; Adsorption; Kinetic studies and reusability test
• ISSN: 0141-8130; 1879-0003; 1879-0003
• DOI: 10.1016/j.ijbiomac.2017.07.007

The chitosan/polyvinyl alcohol/TiO2 composite was synthesized. Two different degrees of deacetylation of chitosan were prepared by hydrolysis to compare the effectiveness of them. The composite was analyzed via field emission scanning electron microscopy, Fourier transform infrared, X-ray diffraction, thermal gravimetric analysis, weight loss test and adsorption study. The FTIR and XRD results proved the interaction among chitosan, PVA and TiO2 without any chemical reaction. It was found that, chitosan with higher degree of deacetylation has better stability. Furthermore, it also showed that higher DD of chitosan required less time to reach equilibrium for methyl orange. The adsorption followed the pseudo-second-order kinetic model. The Langmuir and Freundlich isotherm models were fitted well for isotherm study. Adsorption capacity was higher for the composite containing chitosan with higher DD. The dye removal rate was independent of the dye’s initial concentration. The adsorption capacity was increased with temperature and it was found from reusability test that the composite containing chitosan with higher DD is more reusable. It was notable that adsorption capacity was even after 15 runs. Therefore, chitosan/PVA/TiO2 composite can be a very useful material for dye removal.