Environmentally benign approach towards C–S cross-coupling reaction by organo-copper(II) complex

C–S cross-coupling reaction in water giving an excellent yield of the desired C–S coupled product by using a newly developed Bis[2-(4,5-diphenyl-1 H -imidazol-2-yl)-4-nitrophenolato] copper(II) dehydrate complex as catalyst. Although it was the first report of the synthesis of such a novel organo-co...

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Published inMolecular diversity Vol. 26; no. 1; pp. 505 - 511
Main Authors Singha, Rabindranath, Chettri, Sailesh, Brahman, Dhiraj, Sinha, Biswajit, Ghosh, Pranab
Format Journal Article
LanguageEnglish
Published Cham Springer International Publishing 01.02.2022
Springer Nature B.V
Subjects
Biochemistry
Biomedical and Life Sciences
Catalysis
Chromatography
Copper
Laboratories
Life Sciences
Optimization
Organic Chemistry
Pharmacy
Polymer Sciences
Short Communication
Solvents
Water
Greener protocol
C–S coupling reaction
Metal–organic complex
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ISSN1381-1991
1573-501X
1573-501X
DOI10.1007/s11030-020-10180-5

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Summary:C–S cross-coupling reaction in water giving an excellent yield of the desired C–S coupled product by using a newly developed Bis[2-(4,5-diphenyl-1 H -imidazol-2-yl)-4-nitrophenolato] copper(II) dehydrate complex as catalyst. Although it was the first report of the synthesis of such a novel organo-copper complex from our laboratory, its potential catalytic application was not tested so far. Keeping this in mind and based on our anticipation, we developed a greener route for the C–S coupling reaction. The result is very interesting and comprises the subject matter of this report. Graphic abstract
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ISSN:1381-1991
1573-501X
1573-501X
DOI:10.1007/s11030-020-10180-5