Isolated‐Oxygen‐Vacancy Hardening in Lead‐Free Piezoelectrics

• Published in: Advanced materials (Weinheim) Vol. 34; no. 29; pp. e2202558 - n/a
• Main Authors: Liu, Yi‐Xuan, Qu, Wanbo, Thong, Hao‐Cheng, Zhang, Yang, Zhang, Yunfan, Yao, Fang‐Zhou, Nguyen, Trong Nghia, Li, Jia‐Wang, Zhang, Mao‐Hua, Li, Jing‐Feng, Han, Bing, Gong, Wen, Wu, Haijun, Wu, Chaofeng, Xu, Ben, Wang, Ke
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01.07.2022
• Subjects: Biomedical materials; defect engineering; Hardening; hardening effect; Materials science; Oxygen; oxygen vacancy; Perovskites; piezoelectric; Piezoelectricity; Vacancies; hardening effect; defect engineering; oxygen vacancy; piezoelectric
• ISSN: 0935-9648; 1521-4095; 1521-4095
• DOI: 10.1002/adma.202202558

Defect engineering is a well‐established approach to customize the functionalities of perovskite oxides. In demanding high‐power applications of piezoelectric materials, acceptor doping serves as the state‐of‐the‐art hardening approach, but inevitably deteriorates the electromechanical properties. Here, a new hardening effect associated with isolated oxygen vacancies for achieving well‐balanced performances is proposed. Guided by theoretical design, a well‐balanced performance of mechanical quality factor (Qm) and piezoelectric coefficient (d33) is achieved in lead‐free potassium sodium niobate ceramics, where Qm increases by over 60% while d33 remains almost unchanged. By atomic‐scale Z‐contrast imaging, hysteresis measurement, and quantitative piezoresponse force microscopy analysis, it is revealed that the improved Qm results from the inhibition of both extrinsic and intrinsic losses while the unchanged d33 is associated with the polarization contributions being retained. More encouragingly, the hardening effect shows exceptional stability with increasing vibration velocity, offering potential in material design for practical high‐power applications such as pharmaceutical extraction and ultrasonic osteotomes. A novel strategy is developed for the hardening of piezoelectrics via the mediation of dopant‐exclusive oxygen vacancies to overcome the long‐term issue: the dilemma between the mechanical quality factor and piezoelectricity coefficient. The approach also makes the high‐power performance superior to many state‐of‐the‐art counterparts, offering a possible route to various piezoelectrics for high‐end applications.