Use of chiral sulfoxides in asymmetric synthesis

This report is intended to update the most recent advances in asymmetric synthesis using chiral sulfoxides, focusing on their use as chiral auxiliaries from 2000 to 2006 and their applications in the synthesis of biologically active products. The main purpose of this review is to demonstrate the gro...

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Bibliographic Details
Published inTetrahedron Vol. 62; no. 24; pp. 5559 - 5601
Main Author Pellissier, Hélène
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 12.06.2006
Subjects
de
PTAD
TBDMS
Dodec
dr
BINAP
Tf
MA
Cy
DBU
Boc
Ph
TIPS
Ts
ee
dba
Pr
DIPEA
BF3·Et2O
DIBAL
Py
dppf
Naph
Tol
TBAF
TFAA
LICA
Me
Mes
Pent
Ac
E
LDA
NPM
DMAD
M
Et
Ar
THF
m-CPBA
Cod
Cbz
Ment
DMF
TMSOTf
THP
PMB
AIBN
MOM
Bn
isoB
NMM
LHMDS
NMO
PMP
Bu
HMDS
Born
Hex
TIP
Acac
TMS
Piv
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ISSN0040-4020
1464-5416
DOI10.1016/j.tet.2006.03.093

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Summary:This report is intended to update the most recent advances in asymmetric synthesis using chiral sulfoxides, focusing on their use as chiral auxiliaries from 2000 to 2006 and their applications in the synthesis of biologically active products. The main purpose of this review is to demonstrate the growing potential of these chiral sulfur reagents in transmitting chirality to other centres, establishing the sulfinyl group as one of the most stereocontrolling elements in numerous asymmetric reactions. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2006.03.093