Optimization and design of pigments for heat-insulating coatings

• Published in: Chinese physics B Vol. 19; no. 12; pp. 520 - 525
• Main Author: 王广海 张跃
• Format: Journal Article
• Language: English
• Published: IOP Publishing 01.12.2010
• Subjects: 二氧化钛涂层; 优化设计; 散射模型; 最佳结构; 核壳粒子; 红外热辐射; 隔热涂料; 颜料体积浓度
• ISSN: 1674-1056; 2058-3834
• DOI: 10.1088/1674-1056/19/12/127803

This paper reports that heat insulating property of infrared reflective coatings is obtained through the use of pigments which diffuse near-infrared thermal radiation. Suitable structure and size distribution of pigments would attain maximum diffuse infrared radiation and reduce the pigment volume concentration required. The optimum structure and size range of pigments for reflective infrared coatings are studied by using Kubelka-Munk theory, Mie model and independent scattering approximation. Taking titania particle as the pigment embedded in an inorganic coating, the computational results show that core-shell particles present excellent scattering ability, more so than solid and hollow spherical particles. The optimum radius range of core-shell particles is around 0.3 - 1.6 μm. ~rthermore, the influence of shell thickness on optical parameters of the coating is also obvious and the optimal thickness of shell is 100-300 nm.