Self‐Assembled Monolayers of Bi‐Functionalized Porphyrins: A Novel Class of Hole‐Layer‐Coordinating Perovskites and Indium Tin Oxide in Inverted Solar Cells

• Published in: Angewandte Chemie International Edition Vol. 62; no. 40; pp. e202309831 - n/a
• Main Authors: Hung, Chieh‐Ming, Mai, Chi‐Lun, Wu, Chi‐Chi, Chen, Bo‐Han, Lu, Chih‐Hsuan, Chu, Che‐Chun, Wang, Meng‐Chuan, Yang, Shang‐Da, Chen, Hsieh‐Chih, Yeh, Chen‐Yu, Chou, Pi‐Tai
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 02.10.2023; Wiley Subscription Services, Inc
• Edition: International ed. in English
• Subjects: Carboxylic acids; Chemistry; Chemistry, Multidisciplinary; Dipoles; Energy levels; Functionalized Porphyrins; Hole-Selective Layer; Indium tin oxides; Monolayers; Perovskite Solar Cells; Perovskites; Photovoltaic cells; Physical Sciences; Porphyrins; Science & Technology; Self-Assembled Monolayers; Self-assembly; Solar cells; Transient Absorption Spectroscopy; Self-Assembled Monolayers; Transient Absorption Spectroscopy; PERFORMANCE; ELECTRODES; Hole-Selective Layer; Functionalized Porphyrins; Perovskite Solar Cells
• ISSN: 1433-7851; 1521-3773; 1521-3773
• DOI: 10.1002/anie.202309831

Self‐assembled monolayers (SAMs) offer the advantage of facile interfacial modification, leading to significant improvements in device performance. In this study, we report the design and synthesis of a new series of carboxylic acid‐functionalized porphyrin derivatives, namely AC‐1, AC‐3, and AC‐5, and present, for the first time, a strategy to exploit the large π‐moiety of porphyrins as a backbone for interfacing the indium tin oxide (ITO) electrode and perovskite active layer in an inverted perovskite solar cell (PSC) configuration. The electron‐rich nature of porphyrins facilitates hole transfer and the formation of SAMs, resulting in a dense surface that minimizes defects. Comprehensive spectroscopic and dynamic studies demonstrate that the double‐anchored AC‐3 and AC‐5 enhance SAMs on ITO, passivate the perovskite layer, and function as conduits to facilitate hole transfer, thus significantly boosting the performance of PSCs. The champion inverted PSC employing AC‐5 SAM achieves an impressive solar efficiency of 23.19 % with a high fill factor of 84.05 %. This work presents a novel molecular engineering strategy for functionalizing SAMs to tune the energy levels, molecular dipoles, packing orientations to achieve stable and efficient solar performance. Importantly, our comprehensive investigation has unraveled the associated mechanisms, offering valuable insights for future advancements in PSCs. We have developed a series of new self‐assembled monolayers (SAMs) based on ZnII porphyrin for use as hole‐selective layer (HSL) in inverted perovskite solar cells (PSCs). Our study successfully demonstrates the superior performance of dual carboxylic acid functionalized porphyrins can boost the solar efficiency of PSCs. The outstanding performance of these porphyrin SAMs lies in their inherent self‐assembled properties and the presence of dual carboxylic acid groups that facilitate effective anchoring to both the ITO surface and perovskites.