Non-linear Constitutive Model for the Oligocarbonate Polyurethane Material

• Published in: Chinese journal of polymer science Vol. 32; no. 12; pp. 1666 - 1677
• Main Author: Pawlikowski, Marek
• Format: Journal Article
• Language: English
• Published: Heidelberg Chinese Chemical Society and Institute of Chemistry, CAS 01.12.2014
• Subjects: Abaqus; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Condensed Matter Physics; Constants; Constitutive equations; Constitutive relationships; Finite element method; Industrial Chemistry/Chemical Engineering; Mathematical analysis; Mathematical models; Nonlinearity; Polymer Sciences; Polyurethane resins; 实验测试; 应力应变行为; 本构方程; 本构模型; 聚氨酯材料; 聚碳酸酯二醇; 非线性; Finite elements; Constitutive model; Stress relaxation; Viscoelastic material
• ISSN: 0256-7679; 1439-6203
• DOI: 10.1007/s10118-014-1549-z

The polyurethane, which was the subject of the constitutive research presented in the paper, was based on oligocarbonate diols Desmophen C2100 produced by Bayer？. The constitutive modelling was performed with a view to applying the material as the inlay of intervertebral disc prostheses. The polyurethane was assumed to be non-linearly viscohyperelastic, isotropic and incompressible. The constitutive equation was derived from the postulated strain energy function. The elastic and rheological constants were identified on the basis of experimental tests, i.e. relaxation tests and monotonic uniaxial tests at two different strain rates, i.e. λ= 0.1 min-1 and λ= 1.0 min-1. The stiffness tensor was derived and introduced to Abaqus？finite element（FE） software in order to numerically validate the constitutive model. The results of the constants identification and numerical implementation show that the derived constitutive equation is fully adequate to model stress-strain behavior of the polyurethane material.