Miniemulsion Cross-linking： A Convenient Route to Hollow Polymeric Nanocapsule with a Liquid Core

Miniemulsion stabilized by poly（2-（dimethylamino） ethyl methacrylate）-block-poly（butyl methylacrylate）（PDMAEMA-b-PBMA） diblock copolymers has been used as liquid templates for the synthesis of polymer nanocapsules via quaternization cross-linking of PDMAEMA segments of the copolymer by 1,2-bis（2-iod...

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Bibliographic Details
Published inChinese journal of polymer science Vol. 34; no. 5; p. 523
Main Authors Wu, Lin, Pang, Tao, Guan, Ye-bin
Format Journal Article
LanguageEnglish
Published Beijing Chinese Chemical Society and Institute of Chemistry, CAS 01.04.2016
Subjects
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Copolymers
Crosslinking
Industrial Chemistry/Chemical Engineering
Liquids
Molecular weight
Nanostructure
Polymer Sciences
Segments
Synthesis
交联剂
交联聚合物
嵌段共聚物
液芯
空心
简便
纳米胶囊
细乳液
Nanocapsule
Miniemulsion
Cross-linking
Block copolymer
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ISSN0256-7679
1439-6203
DOI10.1007/s10118-016-1784-6

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Summary:Miniemulsion stabilized by poly（2-（dimethylamino） ethyl methacrylate）-block-poly（butyl methylacrylate）（PDMAEMA-b-PBMA） diblock copolymers has been used as liquid templates for the synthesis of polymer nanocapsules via quaternization cross-linking of PDMAEMA segments of the copolymer by 1,2-bis（2-iodoethoxy）ethane（BIEE） crosslinkers. PDMAEMA-b-PBMAs here as a stabilizer in miniemulsion with different molecular weights led to a size variation in diameters of nanocapsules, demonstrating the capsules have potential design capability of this technique. The solution behavior of the capsules has been also investigated in this paper.
Bibliography:linking methacrylate dimethylamino copolymer polymerization weights stabilized capsules diameters butyl
Miniemulsion stabilized by poly（2-（dimethylamino） ethyl methacrylate）-block-poly（butyl methylacrylate）（PDMAEMA-b-PBMA） diblock copolymers has been used as liquid templates for the synthesis of polymer nanocapsules via quaternization cross-linking of PDMAEMA segments of the copolymer by 1,2-bis（2-iodoethoxy）ethane（BIEE） crosslinkers. PDMAEMA-b-PBMAs here as a stabilizer in miniemulsion with different molecular weights led to a size variation in diameters of nanocapsules, demonstrating the capsules have potential design capability of this technique. The solution behavior of the capsules has been also investigated in this paper.
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ISSN:0256-7679
1439-6203
DOI:10.1007/s10118-016-1784-6