Syntheses, design strategies, and photocatalytic charge dynamics of metal-organic frameworks (MOFs): a catalyzed photo-degradation approach towards organic dyes

• Published in: Catalysis science & technology Vol. 11; no. 12; pp. 3946 - 3989
• Main Authors: Singh, Ayushi, Singh, Ashish Kumar, Liu, Jianqiang, Kumar, Abhinav
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 21.06.2021
• Subjects: Coordination polymers; Drug delivery systems; Dyes; Metal-organic frameworks; Nanoparticles; Organic chemistry; Photocatalysis; Photodegradation; Wastewater
• ISSN: 2044-4753; 2044-4761
• DOI: 10.1039/d0cy02275f

Metal-organic frameworks (MOFs) or coordination polymers (CPs) are regarded as new variety of materials that find potential applications in several areas such as gas/small molecule absorption/separation, gas storage, membranes, and drug delivery system. Also, MOF-incorporating nanoparticles display activity towards various catalytic/electrocatalytic/photocatalytic processes. However, the application of pure metal-organic frameworks as photocatalysts has been recently explored. Further, computational studies on MOFs/CPs add newer insight to better understand the mechanistic pathways through which this new class of materials displays photocatalytic properties. The presented perspective emphasizes the general introduction of syntheses, design strategies and structures of photoactive metal-organic frameworks, and the plausible mechanistic pathways through which these MOFs display photocatalytic degradation of organic molecules in particular organic dyes that are usually present in wastewater discharge from industries. The presented review focuses on design strategies to develop tailor-made MOFs/CPs of main group, transition and inner-transition elements and their photocatalytic properties to decompose dyes in wastewater discharge and their photocatalytic mechanism.