Efficient Synthesis of Pyrrolo[1,2-f]phenanthridine Derivatives via Dipolar Cycloaddition of Phenanthridine, Activated Acetylenes, and Ethyl Bromopyruvate

The three-component reactions of phenanthridine, activated acetylenes, and ethyl bromopyruvate through both of simultaneous and stepwise process are surveyed. The reactions afforded the corresponding pyrrolo[1,2-f]phenanthridine derivatives in good yields without using any catalyst and activation. [...

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Published inSynthetic communications Vol. 44; no. 1; pp. 76 - 81
Main Authors Mehrabi, Hossein, Pishahang, Jaleh
Format Journal Article
LanguageEnglish
Published PHILADELPHIA Taylor & Francis Group 02.01.2014
Taylor & Francis
Taylor & Francis Ltd
Subjects
Chemistry
Chemistry, Organic
Ethyl bromopyruvate
phenanthridine
Physical Sciences
pyrrolo[1,2-f]phenanthridines
Science & Technology
three-component reactions
three-component reactions
2-f]phenanthridines
ANALOGS
AZOMETHINE YLIDES
pyrrolo
AGENTS
Ethyl bromopyruvate
phenanthridine
DIMETHYL ACETYLENEDICARBOXYLATE
Online AccessGet full text
ISSN0039-7911
1532-2432
DOI10.1080/00397911.2013.789525

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Summary:The three-component reactions of phenanthridine, activated acetylenes, and ethyl bromopyruvate through both of simultaneous and stepwise process are surveyed. The reactions afforded the corresponding pyrrolo[1,2-f]phenanthridine derivatives in good yields without using any catalyst and activation. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resource(s): Full experimental and spectral details.]
Bibliography:SourceType-Scholarly Journals-1
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ISSN:0039-7911
1532-2432
DOI:10.1080/00397911.2013.789525