A near-room-temperature organic–inorganic hybrid ferroelectric: [C 6 H 5 CH 2 CH 2 NH 3 ] 2 [CdI 4 ]

An organic–inorganic hybrid compound, [C 6 H 5 CH 2 CH 2 NH 3 ] 2 [CdI 4 ], exhibits a reversible ferroelectric phase transition at 301/297 K. Switchable dielectric constant, second harmonic generation, and pyroelectricity were synchronously observed accompanied by the order–disorder phase transitio...

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Published inChemical communications (Cambridge, England) Vol. 53; no. 42; pp. 5764 - 5766
Main Authors Huang, Bo, Sun, Lin-Ying, Wang, Sha-Sha, Zhang, Jian-Yu, Ji, Cheng-Min, Luo, Jun-Hua, Zhang, Wei-Xiong, Chen, Xiao-Ming
Format Journal Article
LanguageEnglish
Published England 25.05.2017
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ISSN1359-7345
1364-548X
1364-548X
DOI10.1039/C7CC02408H

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Summary:An organic–inorganic hybrid compound, [C 6 H 5 CH 2 CH 2 NH 3 ] 2 [CdI 4 ], exhibits a reversible ferroelectric phase transition at 301/297 K. Switchable dielectric constant, second harmonic generation, and pyroelectricity were synchronously observed accompanied by the order–disorder phase transition. This finding promotes research on molecular ferroelectrics to search for promising multifunctional switching materials at near room temperature.
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/C7CC02408H