Maximum Work Rate Extractable from Energy Fluxes

• Published in: Journal of non-equilibrium thermodynamics Vol. 47; no. 1; pp. 77 - 93
• Main Author: Badescu, Viorel
• Format: Journal Article
• Language: English
• Published: Berlin De Gruyter 01.01.2022; Walter de Gruyter GmbH
• Subjects: Energy; Energy conversion; energy flux; Energy gap; Exergy; Fluxes; Formalism; Solar energy; Solar radiation; work deficiency; work rate
• ISSN: 0340-0204; 1437-4358
• DOI: 10.1515/jnet-2021-0039

A general formalism is developed to evaluate the amount of work extractable from energy fluxes. It covers nonequilibrium cases when the concept of exergy is not relevant. The rate of work deficiency, which has been previously introduced as the total loss of exergy, is defined here as the total loss of work, which would have resulted if all the work were lost to the environment. New performance indicators are proposed. First, the work content factor gives the proportion of extractable work in a given amount of energy. Second, the work deficiency factor is a measure of the potential of improvement for the operation of energy conversion systems. Previous results reported in literature are particular cases of the general results obtained here. The formalism is used to evaluate the work rate extractable from the solar energy flux. Results are shown in cases where solar radiation interacts with materials without energy bandgap (metals) and with energy bandgaps (semiconductors), respectively.