Driven oscillations of the carrier concentration in semiconducting TTF-TCNQ

The large phase change within a few K observed in TTF-TCNQ near 12 K by harmonic mixing of microwaves is explained by assuming a relaxation behaviour of the generation rate of carriers. It is shown that in an a.c. field the non-Ohmic contribution to the conductivity is subject to driven oscillations...

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Bibliographic Details
Published inSolid state communications Vol. 32; no. 7; pp. 557 - 560
Main Author Seeger, K.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.01.1979
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ISSN0038-1098
1879-2766
DOI10.1016/0038-1098(79)90375-2

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Summary:The large phase change within a few K observed in TTF-TCNQ near 12 K by harmonic mixing of microwaves is explained by assuming a relaxation behaviour of the generation rate of carriers. It is shown that in an a.c. field the non-Ohmic contribution to the conductivity is subject to driven oscillations. Although there is no resonance behavior in the amplitude of the signal since both the eigenfrequency and the damping depend on the relaxation times, the resonance manifests itself in the sudden phase change. It is also shown how the recombination relaxation determines the nonlinear d.c. characteristics.
ISSN:0038-1098
1879-2766
DOI:10.1016/0038-1098(79)90375-2