High-precision measurement of the electron spin g factor of trapped atomic nitrogen in the endohedral fullerene N@C60

• Published in: Journal of magnetic resonance (1997) Vol. 290; pp. 12 - 17
• Main Authors: Wittmann, J.J., Can, T.V., Eckardt, M., Harneit, W., Griffin, R.G., Corzilius, B.
• Format: Journal Article
• Language: English
• Published: Elsevier Inc 01.05.2018
• Subjects: EPR; Fullerene; g factor; NMR; Fullerene; NMR; g factor; EPR; Reference
• ISSN: 1090-7807; 1096-0856; 1096-0856
• DOI: 10.1016/j.jmr.2018.02.019

[Display omitted] •The precise g factor of endohedral fullerene N@C60 embedded in solid C60 was measured.•No external or internal g reference was used by combination of EPR and NMR.•Results confirm that nitrogen atom is not interacting with C60 cage orbitals. The electronic g factor carries highly useful information about the electronic structure of a paramagnetic species, such as spin-orbit coupling and dia- or paramagnetic (de-)shielding due to local fields of surrounding electron pairs. However, in many cases, a near “spin-only” case is observed, in particular for light elements, necessitating accurate and precise measurement of the g factors. Such measurement is typically impeded by a “chicken and egg situation”: internal or external reference standards are used for relative comparison of electron paramagnetic resonance (EPR) Larmor frequencies. However, the g factor of the standard itself usually is subject to a significant uncertainty which directly limits the precision and/or accuracy of the sought after sample g factor. Here, we apply an EPR reference-free approach for determining the g factor of atomic nitrogen trapped within the endohedral fullerene C60:N@C60 in its polycrystalline state by measuring the 1H NMR resonance frequency of dispersing toluene at room temperature. We found a value of g=2.00204(4) with a finally reached relative precision of ∼20 ppm. This accurate measurement allows us to directly compare the electronic properties of N@C60 to those found in atomic nitrogen in the gas phase or trapped in other solid matrices at liquid helium temperature. We conclude that spin-orbit coupling in N@C60 at room temperature is very similar in magnitude and of same sign as found in other inert solid matrices and that interactions between the quartet spin system and the C60 molecular orbitals are thus negligible.