Structure formation of fullerene-containing propylene oxide oligomers in deuterium water

Structure formation of propylene oxide oligomers with terminal hydrophobic aliphatic fragment and of oligo(propylene oxides) additionally containing covalently bonded fullerene C 60 in deuterium water was studied by small-angle neutron scattering. Propylene oxide chains containing a long hydrophobic...

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Bibliographic Details
Published inRussian journal of applied chemistry Vol. 86; no. 4; pp. 568 - 574
Main Authors Lebedev, V. T., Kul’velis, Yu. V., Orlova, D. N., Melenevskaya, E. Yu, Nasonova, K. V., Vinogradova, L. V.
Format Journal Article
LanguageEnglish
Published Dordrecht SP MAIK Nauka/Interperiodica 01.04.2013
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
Macromolecular Compounds and Polymeric Materials
Fullerene
Oligomer Chain
Propylene Oxide
Scattering Length Density
Oligomer
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ISSN1070-4272
1608-3296
DOI10.1134/S1070427213040204

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Summary:Structure formation of propylene oxide oligomers with terminal hydrophobic aliphatic fragment and of oligo(propylene oxides) additionally containing covalently bonded fullerene C 60 in deuterium water was studied by small-angle neutron scattering. Propylene oxide chains containing a long hydrophobic fragment undergo organization into spherical micelles, whereas the fullerene(C 60 )-containing derivatives form rodlike structures (elongated “chains” of cross-linked micelles).
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427213040204