Rubia-inspired biogenic synthesis of Cu–ZnO nanocomposites: Dual-modelling of visible light photocatalytic degradation and antibacterial assessment

• Published in: Current research in green and sustainable chemistry Vol. 9; p. 100435
• Main Authors: Mathew Tharayil, Jeevan, Chinnaiyan, Prakash, Sathasivan, Arumugam
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 2024; Elsevier
• Subjects: Cu–ZnO; Dye; Modelling; Photocatalysis; Rubia cordifolia; Rubia cordifolia; Cu–ZnO; Dye; Modelling; Photocatalysis
• ISSN: 2666-0865; 2666-0865
• DOI: 10.1016/j.crgsc.2024.100435

Cu-doped ZnO nanoparticles (NPs) were synthesised using Rubia cordifolia root extract and their photocatalytic degradation and antimicrobial properties were evaluated. Among all dopant concentrations, UV-VIS analysis of 5 % Cu–ZnO NPs revealed a clean shift towards the visible range with a reduction in the band gap from 3.2 eV for pristine ZnO to 2.98 eV. Formed NPs were identified as wurtzite crystal structure (size of 16.67 nm) having functional group of ZnO, using XRD and FTIR analysis. Highest photocatalytic degradation efficiencies of both Alizarine Red (AZ) (80 %) and Rhodamine B (RhB) (82 %) dyes were by 5 % Cu–ZnO NPs. Statistical modelling and optimization were conducted using Response Surface Methodology (RSM) and Adaptive Neuro-Fuzzy Inference System (ANFIS), resulting in development of models having >90 % predictive accuracy. Furthermore, the biogenic Cu–ZnO nanoparticles exhibits effective antimicrobial properties against both gram-positive (S. aureus) and gram-negative (E. coli) bacteria. The biogenic synthesis approach demonstrated enhanced photocatalytic efficiency and antimicrobial properties, suggesting its potential for environmentally friendly applications. [Display omitted] •Green synthesis of a Cu–ZnO nano-photocatalyst was achieved using Rubia Cordifolia root extract.•SEM-EDS, XRD, FTIR, and UV-DRS characterizations confirmed the formation of ZnO nanoparticles.•Cu doping resulted in a reduction in band gap, with 5 wt% Cu–ZnO demonstrating the lowest band gap of 2.98 eV.•Biogenic Cu–ZnO exhibited excellent photocatalytic performance, effectively degrading dyes by over 90 %.•Comparative modelling analysis revealed that ANFIS modelling was more accurate than RSM-CCD modelling.