Photoluminescence properties of color-tunable KLaSiO4:Ce3+,Mn2+phosphors

A series of color-tunable KLaSiO4:Ce3+,Mn2+phosphors were successfully prepared and the luminescent properties were investigated. Upon excitation at 290 nm, the emission spectra of KLaSiO4:Ce3+,Mn2+phosphors included a blue emission band and a red emission band. Increasing the doping concentration o...

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Published inJournal of rare earths Vol. 33; no. 5; pp. 480 - 485
Main Author 常文瑞 王丹 朋兴平 王育华 胡龄之 王静
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.05.2015
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ISSN1002-0721
2509-4963
DOI10.1016/S1002-0721(14)60444-0

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Summary:A series of color-tunable KLaSiO4:Ce3+,Mn2+phosphors were successfully prepared and the luminescent properties were investigated. Upon excitation at 290 nm, the emission spectra of KLaSiO4:Ce3+,Mn2+phosphors included a blue emission band and a red emission band. Increasing the doping concentration of Mn2+ions, the red emission was strengthened considerably, and the blue emission of Ce3+ was reduced, owing to the efficient energy transfer. The composition optimized KLa0.96SiO4:0.02Ce3+,0.02Mn2+sample exhibited the white light emission brightly with the chromaticity coordinates of (0.331, 0.337). Therefore, KLaSiO4:Ce3+, Mn2+could be used as a white phosphor candidate for white light-emitting diodes devices.
Bibliography:11-2788/TF
KLaSiO4:Ce3+,Mn2+; energy transfer; color-tunable; rare earths
A series of color-tunable KLaSiO4:Ce3+,Mn2+phosphors were successfully prepared and the luminescent properties were investigated. Upon excitation at 290 nm, the emission spectra of KLaSiO4:Ce3+,Mn2+phosphors included a blue emission band and a red emission band. Increasing the doping concentration of Mn2+ions, the red emission was strengthened considerably, and the blue emission of Ce3+ was reduced, owing to the efficient energy transfer. The composition optimized KLa0.96SiO4:0.02Ce3+,0.02Mn2+sample exhibited the white light emission brightly with the chromaticity coordinates of (0.331, 0.337). Therefore, KLaSiO4:Ce3+, Mn2+could be used as a white phosphor candidate for white light-emitting diodes devices.
CHANG Wenrui,WANG Dan,PENG Xingping,WANG Yuhua,HU Lingzhi,WANG Jing
ISSN:1002-0721
2509-4963
DOI:10.1016/S1002-0721(14)60444-0