Nanoarchitectonics of metal–organic frameworks having hydroxy group for adsorption, catalysis, and sensing

• Published in: Journal of industrial and engineering chemistry (Seoul, Korea) Vol. 119; pp. 181 - 192
• Main Authors: Lee, Gyudong, Hossain, Md. Abul, Yoon, Minyoung, Jhung, Sung Hwa
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 25.03.2023; 한국공업화학회
• Subjects: Adsorption; Catalysis; Functionalization; Hydroxy group; Metal–organic framework; 화학공학; Metal–organic framework; Hydroxy group; Catalysis; Adsorption; Functionalization
• ISSN: 1226-086X; 1876-794X
• DOI: 10.1016/j.jiec.2022.12.005

[Display omitted] Functionalized metal–organic frameworks (MOFs) are very popular because of their various applications, designable functional sites, and facile preparation. MOFs composed of a hydroxy group on linkers or on grafted species are also attractive based on the possible applications of loaded –OH groups. In this review, MOFs with –OH groups (termed MOF-OHs) will be discussed in the view of both preparation and applications. Direct synthesis from linker precursors having –OH groups and post-synthetic modification will be delineated for the preparation of MOF-OHs. The applications of MOF-OHs in adsorption, catalysis, and sensing will also be dealt. This review shows that MOF-OHs can be facilely prepared via direct synthesis and post-synthetic modification; have various applications in adsorption, catalysis, etc. mainly because of the contribution of the loaded hydroxy groups. Finally, future prospects will be suggested for relevant research.