High quantum yield and unusual photoluminescence behaviour in tetrahedral manganese( ii ) based on hybrid compounds

Two novel tetrahedral manganese( ii ) complexes, ( N -methylpiperidinium)MnCl 4 ( 1 ) and ( N -methylpyrrolidinium)MnCl 4 ( 2 ), with clearly distinct fluorescence characteristics were synthesized through organic cation modulation. Compound 1 exhibits prominent green luminescence with a high quantum...

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Published inInorganic chemistry frontiers Vol. 5; no. 10; pp. 2615 - 2619
Main Authors Wei, Yan-Li, Jing, Jing, Shi, Chao, Ye, Heng-Yun, Wang, Zhong-Xia, Zhang, Yi
Format Journal Article
LanguageEnglish
Published London Royal Society of Chemistry 01.10.2018
Subjects
Crystallography
Fluorescence
Inorganic chemistry
Manganese
Photoluminescence
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ISSN2052-1553
2052-1545
2052-1553
DOI10.1039/C8QI00793D

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Summary:Two novel tetrahedral manganese( ii ) complexes, ( N -methylpiperidinium)MnCl 4 ( 1 ) and ( N -methylpyrrolidinium)MnCl 4 ( 2 ), with clearly distinct fluorescence characteristics were synthesized through organic cation modulation. Compound 1 exhibits prominent green luminescence with a high quantum yield of 79.37% and 2 emits unusual red emission at 611 nm.
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ISSN:2052-1553
2052-1545
2052-1553
DOI:10.1039/C8QI00793D