Bonding of organometallic fragments to polyoxometallates

• Published in: Journal of organometallic chemistry Vol. 475; no. 1; pp. 149 - 155
• Main Author: Calhorda, M.J.
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Lausanne Elsevier B.V 26.07.1994; Elsevier Science
• Subjects: Atomic and molecular physics; Calculations and mathematical techniques in atomic and molecular physics (excluding electron correlation calculations); Electronic structure of atoms, molecules and their ions: theory; Exact sciences and technology; Extended Hückel calculations; Molybdenum; Niobium; Physics; Polyoxometallate; Rhodium; Semi-empirical and empirical calculations (differential overlap, hückel, ppp methods, etc.); Statistical model calculations (including Thomas-Fermi and Thomas-Fermi-Dirac models); Titanium; Titanium; Polyoxometallate; Extended Hückel calculations; Rhodium; Molybdenum; Niobium; Inorganic compounds; Frontier orbital; Theoretical study; HMO calculations; Molybdenum complexes; Niobium complexes; Isomers; Charge distribution; Oxo complex; Anions; Electronic structure; Reactivity; Dinuclear complex; Chemical bonds; Hapto complex; Rhodium complexes
• ISSN: 0022-328X; 1872-8561
• DOI: 10.1016/0022-328X(94)84017-2

The chemistry of polyoxometallates has become a subject of great interest, since these compounds have been considered suitable models for understanding