ChemInform Abstract: Enantioselective Synthesis of Allylboronates and Allylic Alcohols by Copper-Catalyzed 1,6-Boration
Highly enantioselective synthesis of δ‐hydroxy‐β,γ‐unsaturated carbonyl compounds is achieved by copper‐catalyzed 1,6‐boration using bis(pinacolato)diboron in the presence of a Cu(I) Josiphos complex as catalyst.
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| Published in | ChemInform Vol. 45; no. 40; p. no |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
30.09.2014
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
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| ISSN | 0931-7597 1522-2667 |
| DOI | 10.1002/chin.201440034 |
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| Abstract | Highly enantioselective synthesis of δ‐hydroxy‐β,γ‐unsaturated carbonyl compounds is achieved by copper‐catalyzed 1,6‐boration using bis(pinacolato)diboron in the presence of a Cu(I) Josiphos complex as catalyst. |
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| AbstractList | Highly enantioselective synthesis of δ‐hydroxy‐β,γ‐unsaturated carbonyl compounds is achieved by copper‐catalyzed 1,6‐boration using bis(pinacolato)diboron in the presence of a Cu(I) Josiphos complex as catalyst. Highly enantioselective synthesis of [delta]-hydroxy-[beta],[gamma]-unsaturated carbonyl compounds is achieved by copper-catalyzed 1,6-boration using bis(pinacolato)diboron in the presence of a Cu(I) Josiphos complex as catalyst. [PUBLICATION ABSTRACT] |
| Author | Madec, Amael G. E. Lam, Hon Wai Luo, Yunfei Roy, Iain D. |
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| Cites_doi | 10.1002/anie.201310380 |
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| Copyright | 2014 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany 2014 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany |
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| References | Yunfei Luo, Iain D. Roy, Amael G. E. Madec, Hon Wai Lam, Enantioselective Synthesis of Allylboronates and Allylic Alcohols by Copper-Catalyzed 1,6-Boration., Angew. Chem., Int. Ed., 2014, 53, 4186-4190. DOI: 10.1002/anie.201310380 2014; 53 e_1_2_2_1_2 |
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| Snippet | Highly enantioselective synthesis of δ‐hydroxy‐β,γ‐unsaturated carbonyl compounds is achieved by copper‐catalyzed 1,6‐boration using bis(pinacolato)diboron in... Highly enantioselective synthesis of [delta]-hydroxy-[beta],[gamma]-unsaturated carbonyl compounds is achieved by copper-catalyzed 1,6-boration using... |
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| SubjectTerms | boration catalysis catalysis, phase‐transfer catalysis diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) hydroboration hydroboration, boration hydroxylation medicinal chemistry pharmacology pharmacology, medicinal chemistry, vaccines, serums phase-transfer catalysis serums vaccines |
| Title | ChemInform Abstract: Enantioselective Synthesis of Allylboronates and Allylic Alcohols by Copper-Catalyzed 1,6-Boration |
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