ChemInform Abstract: Enantioselective Synthesis of Allylboronates and Allylic Alcohols by Copper-Catalyzed 1,6-Boration

Highly enantioselective synthesis of δ‐hydroxy‐β,γ‐unsaturated carbonyl compounds is achieved by copper‐catalyzed 1,6‐boration using bis(pinacolato)diboron in the presence of a Cu(I) Josiphos complex as catalyst.

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Bibliographic Details
Published in	ChemInform Vol. 45; no. 40; p. no
Main Authors	Luo, Yunfei, Roy, Iain D., Madec, Amael G. E., Lam, Hon Wai
Format	Journal Article
Language	English
Published	Weinheim WILEY-VCH Verlag 30.09.2014 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Subjects	boration catalysis catalysis, phase‐transfer catalysis diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) hydroboration hydroboration, boration hydroxylation medicinal chemistry pharmacology pharmacology, medicinal chemistry, vaccines, serums phase-transfer catalysis serums vaccines
Online Access	Get full text
ISSN	0931-7597 1522-2667
DOI	10.1002/chin.201440034

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Summary:	Highly enantioselective synthesis of δ‐hydroxy‐β,γ‐unsaturated carbonyl compounds is achieved by copper‐catalyzed 1,6‐boration using bis(pinacolato)diboron in the presence of a Cu(I) Josiphos complex as catalyst.
Bibliography:	ArticleID:CHIN201440034 ark:/67375/WNG-MCC63WGZ-P istex:F4B4AD8F42FAE684EE7A493542A4349B825215EF ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201440034