Mid‐infrared detection and characterization of refractory inclusions in CM and CO chondrites: A non‐destructive approach for returned space samples

• Published in: Meteoritics & planetary science Vol. 60; no. 3; pp. 544 - 569
• Main Authors: Charlier, Jean, Aléon‐Toppani, Alice, Brunetto, Rosario, Aléon, Jérôme, Borondics, Ferenc
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc 01.03.2025
• Subjects: Algorithms; Astronomy; Celestial bodies; Chondrites; Electron microscopy; Hyperspectral imaging; Inclusions; Infrared spectroscopy; Machine learning; Mineralogy; Minerals; Remote sensing; Solar system; Space missions; Spectroscopy; Spectrum analysis; Tracers
• ISSN: 1086-9379; 1945-5100; 1945-5100
• DOI: 10.1111/maps.14314

Refractory inclusions (RIs) in chondrites are widely used as tracers of early solar system formation conditions. In the context of sample‐return missions, a non‐destructive and non‐invasive analytical tool that can rapidly detect and characterize RIs in space samples during their early phase of study is highly needed. Here, we performed mid‐infrared (MIR) fine‐scale hyperspectral imaging over large fields of view to detect RIs in CM and CO chondrites. A database of MIR spectra of typical RIs minerals was built (1) to support future remote sensing observations in astronomical environments and (2) to develop a detection method based on machine‐learning algorithms and spectral distance between sample and reference minerals. With this method, up to 96.5% of the RI content is detected in a meteorite section. Further comparison between scanning electron microscopy and spot analysis acquired in reflectance in the full MIR range shows that RIs can be classified following their mineralogy based on infrared (IR) properties. Finally, we show that the relative OH content of several RIs in CM chondrites determined from IR spectroscopy can be used to infer the extent of modification caused by aqueous alteration on the asteroidal parent body.