Nanostructured Titanium/Diamond-Like Carbon Multilayer Films: Deposition, Characterization, and Applications

• Published in: ACS applied materials & interfaces Vol. 3; no. 11; pp. 4268 - 4278
• Main Authors: Dwivedi, Neeraj, Kumar, Sushil, Malik, Hitendra K
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 23.11.2011
• Subjects: Biomedical Research - instrumentation; Diamond - chemistry; Nanostructures - chemistry; Titanium - chemistry; optical properties; electrical properties; biomedical applications; SEM; SIMS; nanomechanical properties; thin films
• ISSN: 1944-8244; 1944-8252; 1944-8252
• DOI: 10.1021/am200939j

Titanium/diamond-like carbon multilayer (TDML) films were deposited using a hybrid system combining radio frequency (RF)-sputtering and RF-plasma enhanced chemical vapor deposition (PECVD) techniques under a varied number of Ti/diamond-like carbon (DLC) bilayers from 1 to 4, at high base pressure of 1 × 10–3 Torr. The multilayer approach was used to create unique structures such as nanospheres and nanorods in TDML films, which is confirmed by scanning electron microscopy (SEM) analysis and explained by a hypothetical model. Surface composition was evaluated by X-ray photoelectron spectroscopy (XPS), whereas energy dispersive X-ray analysis (EDAX) and time-of-flight secondary ion mass spectrometer (ToF-SIMS) measurements were performed to investigate the bulk composition. X-ray diffraction (XRD) was used to evaluate the phase and crystallinity of the deposited TDML films. Residual stress in these films was found to be significantly low. These TDML films were found to have excellent nanomechanical properties with maximum hardness of 41.2 GPa. In addition, various nanomechanical parameters were calculated and correlated with each other. Owing to metallic interfacial layer of Ti in multilayer films, the optical properties, electrical properties, and photoluminescence were improved significantly. Due to versatile nanomechanical properties and biocompatibility of DLC and DLC based films, these TDML films may also find applications in biomedical science.